Three complexes of manganese(II) based on a new semirigid tetracarboxylate and N-containing ligands: Synthesis, crystal structures and magnetic properties

Fan, Yida; Si, Chang-Dai; Hou, C.; Yao, Xiao-Qiang; Hu, Dong‐Cheng; Yang, Yun-Xia; Liu, Jiacheng

doi:10.1016/j.poly.2015.06.012

Cited by 14 publications

(2 citation statements)

References 33 publications

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“…chelating and monodenate modes. The two Cd1 ions are connected by two carboxylate groups in an alternative chelating and monodenate mode to form a binuclear unit [ 41 ]. In the unit, the distance between the two Cd(II) ions is 8.173 Å. Cd2 is hepta-coordinated and the seven-coordinated geometry is satisfied by two N atoms from one 2,2′-bipy ligand and five O atoms from two partially deprotonated H 2 L ligands ( Scheme S1a,b ).…”

Section: Resultsmentioning

confidence: 99%

Two Chemically Stable Cd(II) Polymers as Fluorescent Sensor and Photocatalyst for Aromatic Dyes

Wang

et al. 2018

Polymers

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Two new 2D Cd(II)-based coordination polymers (CPs), viz. [Cd2(H2L)2(2,2’-bipy)2] (1) and [Cd(L)0.5(phen)·0.5H2O] (2), have been constructed using ethylene glycol ether bridging tetracarboxylate ligand 5,5′(4,4′-phenylenebis(methyleneoxy)) diisophthalic acid (H4L). Both CPs behaved as profound fluorescent sensor for Fe3+ ion and nitro-aromatics (NACs), specifically 2,4,6-trinitrophenol (TNP). The stability at elevated temperature and photocatalytic behaviors of both 1 and 2 for photo-decomposition of aromatic dyes have also been explored. An attempt has been made to explore the plausible mechanism related with the decrease in fluorescence intensity of 1 and 2 in presence of NACs using theoretical calculations. Additionally, the probable mechanism of photo catalysis by 1 and 2 to photo-degrade aromatic dyes has been explained using density of states (DOS) calculations.

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Section: Resultsmentioning

confidence: 99%

Two Chemically Stable Cd(II) Polymers as Fluorescent Sensor and Photocatalyst for Aromatic Dyes

Wang

et al. 2018

Polymers

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“…Recently, a class of semi-rigid multicarboxylic acid molecules has attracted the attention of researchers [36,37,32,[38][39][40][41][42][43][44]. They generally consist of several benzene ring moieties.…”

Section: Introductionmentioning

confidence: 99%

Structural characterization of three semi-rigid tetracarboxylate-containing transition-metal coordination polymers

Huang

2016

Polyhedron

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A series of Zn/Cd coordination polymers constructed from 1,4-naphthalenedicarboxylate and N-donor ligands: Syntheses, structures and luminescence sensing of Cr3+ in aqueous solutions

Fan

et al. 2016

Journal of Solid State Chemistry

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Three complexes of manganese(II) based on a new semirigid tetracarboxylate and N-containing ligands: Synthesis, crystal structures and magnetic properties

Cited by 14 publications

References 33 publications

Two Chemically Stable Cd(II) Polymers as Fluorescent Sensor and Photocatalyst for Aromatic Dyes

Two Chemically Stable Cd(II) Polymers as Fluorescent Sensor and Photocatalyst for Aromatic Dyes

Structural characterization of three semi-rigid tetracarboxylate-containing transition-metal coordination polymers

A series of Zn/Cd coordination polymers constructed from 1,4-naphthalenedicarboxylate and N-donor ligands: Syntheses, structures and luminescence sensing of Cr3+ in aqueous solutions

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