Three-dimensional skeleton assembled by carbon nanotubes/boron nitride as filler in epoxy for thermal management materials with high thermal conductivity and electrical insulation

Yang, Wang; Wang, Yifan; Li, Yun; Gao, Can; Tian, Xiaojuan; Wu, Ni; Geng, Zishuo; Che, Sai; Yang, Fan; Li, Yongfeng

doi:10.1016/j.compositesb.2021.109168

Cited by 92 publications

(32 citation statements)

References 47 publications

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“…(b) Tensile strength and elastic modulus of EP, CFC/EP, and CFC@CNT/EP. (c) Mechanical properties of CFC@CNT/EP and epoxy-based composites reported in previous work. − (d) Tensile strength and elastic modulus of CFC@CNT/EP after 100 cycles bending. (e) In-plane and through-plane thermal conductivity of CFC@CNT/EP after 100 cycles bending.…”

Section: Resultsmentioning

confidence: 98%

Design of Interconnected Carbon Fiber Thermal Management Composites with Effective EMI Shielding Activity

Qian

Yan

et al. 2022

ACS Appl. Mater. Interfaces

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Heat dissipation efficiency and electromagnetic interference (EMI) shielding performance are vital to integration, miniaturization, and application of electronic devices. Flexible and designable polymer-based composites are promising candidates but suffer from unavoidable interfacial thermal resistances, anisotropic thermal conductivity, and low shielding of EMI limiting application. Herein, multifunctional epoxy resin (EP)-based composites with an interconnected carbon fibers (CFs) network structure containing a low thermal resistance interfacial were prepared by high-temperature calcination and infiltration. The coherent heat and electron transfer pathways constructed with self-oriented CFs cloth connected by carbon nanotubes (CNTs) converted from leaf-shaped zeolitic imidazolate frameworks (ZIF-L) and stable magnetic property provided by cobalt nanoparticles contained in the CNTs made composites to an integrated in-plane thermal conductivity of up to 7.50 W m −1 K −1 , a through-plane thermal conductivity of 1.96 W m −1 K −1, and an EMI shielding effectiveness of 38.4 dB. Furthermore, the mechanical properties of CFs and the junction effect of CNTs endowed the composites with stability of mechanical property, thermal conductivity, and EMI shielding effectiveness after multiple bendings. The finite element simulation further verified the advantage of CFs network linked by CNTs on heat transfer. This work provides the desired design for the construction of a multifunctional polymer-based composite used in advanced electronic equipment.

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Section: Resultsmentioning

confidence: 98%

Design of Interconnected Carbon Fiber Thermal Management Composites with Effective EMI Shielding Activity

Qian

Yan

et al. 2022

ACS Appl. Mater. Interfaces

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“…c TCE with MXene/graphene loading. d Comparison of thermal conductivity of different 3D network filled composites: spherical BN/PDMS [ 54 ], MXene/PEG [ 55 ], PEG/MXene/GR [ 36 ], PA6/GO/CF [ 37 ], BN30C3/MHDPE [ 56 ], Epoxy/BNNS/CNTs [ 18 ], PDMS/T-SGM [ 57 ], PEG/c-GA/MF [ 58 ], Epoxy/BN-PVDF [ 59 ], PEG/BNF scaffold [ 29 ], MXene/PCM [ 60 ], CCA@rGO/PDMS [ 51 ], PEG/PPF@MXene [ 61 ] …”

Section: Resultsmentioning

confidence: 99%

Interconnected MXene/Graphene Network Constructed by Soft Template for Multi-Performance Improvement of Polymer Composites

et al. 2022

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The multi-functionalization of polymer composites refers to the ability to connect multiple properties through simple structural design and simultaneously achieve multi-performance optimization. The large-scale design and mass production to realize the reasonable structure design of multifunctional polymer composites are urgently remaining challenges. Herein, the multifunctional MXene/graphene/polymer composites with three-dimensional thermally and electrically conductive network structures are fabricated via the utilization of the microstructure of the soft template, and a facile dispersion dip-coating approach. As a result, the polymer composites have a multi-performance improvement. At the MXene and graphene content of 18.7 wt%, the superior through-plane thermal conductivity of polymer composite is 2.44 W m−1 K−1, which is 1118% higher than that of the polymer matrix. The electromagnetic interference (EMI) shielding effectiveness of the sample reaches 43.3 dB in the range of X-band. And the mechanical property of the sample has advanced 4 times compared with the polymer matrix. The excellent EMI shielding and thermal management performance, along with the effortless and easy-to-scalable producing techniques, imply promising perspectives of the polymer composites in the next-generation smart electronic devices.

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“…Herein, to evidently improve the polymer/BNNSs nanocomposite properties, some design mentalities, such as improving the dispersion and orientation of BNNS, promoting the BNNS to selectively distribute at different blending phases interfaces, and designing the bioinspired structures, are adopted by many researchers to date. [ 93–97 ] In this part, the frequently‐used structural designs and preparation methods for polymer/BNNSs nanocomposites in recent years are introduced.…”

Section: Preparation For Bnns‐based Polymer Nanocompositesmentioning

confidence: 99%

2D Boron Nitride Nanosheets for Smart Thermal Management and Advanced Dielectrics

Zhou

Zhang

et al. 2022

Adv Materials Inter

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With the rapid development of electronic devices toward the miniaturization, integration, and multi‐functionalization, the device stability, reliability, and service life face significant challenges due to the greatly increased heat accumulation. Therefore, it is highly desired to develop efficient thermal dissipation materials in thermal management. Thermally conductive polymer composites are expected to be widely applied in 5G communication, electronic packaging, and energy storage, owing to the ease of processing, good flexibility, low cost, etc. Boron nitride nanosheet (BNNS) is generally used as highly thermal conductive nanofillers for greatly improving the thermal conductivity of polymer. Mass production of high quality BNNS with desired properties and the structural design principles and fabrication methods for polymer/BNNS nanocomposites are critical to achieve extensive applications. Here, this review summarizes the latest advancement of the preparation method of BNNS and its polymer nanocomposites, as well as the innovatively structural design for observably improving the thermal management capability and energy storage performance of polymer/BNNS nanocomposites, expecting to offer some guidance on how to massively fabricate the BNNS and highly thermally conductive polymer composites.

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Three-dimensional skeleton assembled by carbon nanotubes/boron nitride as filler in epoxy for thermal management materials with high thermal conductivity and electrical insulation

Cited by 92 publications

References 47 publications

Design of Interconnected Carbon Fiber Thermal Management Composites with Effective EMI Shielding Activity

Design of Interconnected Carbon Fiber Thermal Management Composites with Effective EMI Shielding Activity

Interconnected MXene/Graphene Network Constructed by Soft Template for Multi-Performance Improvement of Polymer Composites

2D Boron Nitride Nanosheets for Smart Thermal Management and Advanced Dielectrics

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