Abstract-Through silicon vias (TSVs) are key enablers of 3D integration technologies which, by vertically stacking and interconnecting multiple chips, achieve higher performances, lower power and a smaller footprint. Copper is the most commonly used conductor to fill TSVs; however, copper has a high thermal expansion mismatch in relation to the silicon substrate. This mismatch results in a large accumulation of thermomechanical stress when TSVs are exposed to high temperatures and/or temperature cycles, potentially resulting in device failure.In this paper, we demonstrate 300 µm long, 7:1 aspect ratio TSVs with Invar as a conductive material. The entire TSV structure can withstand at least 100 thermal cycles from -50• C to 190• C and at least one hour at 365 • C, limited by the experimental setup. This is possible thanks to matching coefficients of thermal expansion (CTE) of the Invar via conductor and of silicon substrate. This results in thermomechanical stresses that are one order of magnitude smaller compared to copper TSV structures with identical geometries, according to finite element modelling. Our TSV structures are thus a promising approach enabling 2.5D and 3D integration platforms for high-temperature and harsh-environment applications.