Soil aeration is a key parameter for sustainable and productive agriculture. The intensification of agricultural activity in Greenland involves land use (LU) and LU change, affecting the soil-air phase. The combined effects of natural compaction (bulk density, ρ b ), texture (texture uniformity index; TUI), and LU on the soil-air phase of subarctic soils are not well known. This study aims to identify and compare the main drivers for air-filled porosity (ε) and soil-structure changes within and across sites in Greenland and Denmark. We analyzed comprehensive data sets of ε, relative gas diffusivity D p /D o ), and air-permeability (k a ) measured on intact soil samples from South Greenland (pasture) and Denmark (cultivated, urban, and forest). The mechanical robustness of the air phase was evaluated by linear models of ε as a function of ρ b (H-model). The ratio of k a to D p /D o served as a soil-structure index (Ω); the latter significantly correlated to TUI. The Greenlandic pasture soils did not show signs of well-developed soil structure (low Ω-values), whereas low H-values suggested the soils were mechanically robust compared to similar-textured cultivated soils. The soil-air characteristic curve (ε vs. pF) was parameterized, and the moisture control parameter was accurately predicted by TUI and LU (R 2 = .95). Overall, the ρ b was found to control the air-phase functions within a field. However, considering changes in ε-levels across different fields, texture, LU, and other environmental factors became statistically more relevant than ρ b . A modeled response surface for changes in ε with soil conditions may, in perspective, be useful for better-predicting gas transport in soil, both within and across fields.