One of the alternative sustainable and green construction materials to concrete is timber. Timber is of numerous varieties, and this acts as a barrier to the extent of its usage, especially in structural application. Despite many researches on wood's mechanical and physical properties, only a few are geared toward the structural application of wood. The present work investigated the mechanical properties of five timber species; Gmelina arborea, Tectona grandis (Teak), Terminalia superba (Afara), Ayin (Anogeissus leiocarpus), and Acacia (Robinia pseudoacacia), to determine their suitability for constructing long-span roof trusses. These are available in the South Western part of Nigeria. Their mechanical properties; bending strength, compressive strength, shear strength, tensile strength, Modulus of Elasticity (MOE), Modulus of Rupture (MOR), and density, were determined in the laboratory. The results obtained showed that all the timber types, except Terminalia superba (Afara), have higher values of mechanical properties than the values that are obtainable for classes of strength D30 to class D70 in the British Code of Practice. It means these species are of higher quality than the stipulated strength classes in the British code. The results also show that the order of relevance of the species for structural design (or work) is Acacia (Robinia pseudoacacia), Ayin (Anogeissus leiocarpus), Gmelina Arborea, and Tectona grandis (Teak). Terminalia superba (Afara) is not recommended for structural works.