In-depth understanding of the photoconductivity and photocarrier density at the interface is of great significance for improving the performance of optoelectronic devices. However, the extraction of the photoconductivity and photocarrier density at the heterojunction interface still remains elusive. Herein, we have obtained the photoconductivity and photocarrier density of the 173 nm-Sb2Se3/Si (type-Ⅰ heterojunction) and 90 nm-Sb2Se3/Si (type-Ⅱ heterojunction) utilizing the terahertz (THz) time-domain spectroscopy (THz-TDS) and theoretical Drude model. Since type-Ⅰ heterojunction accelerates carrier recombination and type-Ⅱ heterojunction accelerates carrier separation, the photoconductivity and photocarrier density of type-Ⅱ heterojunction (21.8×104 S/m, 1.5×1015 cm-3) are higher than that of type-Ⅰ heterojunction (11.8×104 S/m, 0.8×1015 cm-3). These results demonstrate that the type-Ⅱ heterojunction is superior to type-Ⅰ heterojunction for THz wave modulation. This work highlights the THz-TDS as an effective tool to study the photoconductivity and photocarrier density at the heterojunction interface. In turn, the intriguing interfacial photoconductivity effect provides a way to improve the THz wave modulation performance.