Titanocene thiolates [Ti]Cl(SCHR-2- C4H3S) and [Ti](SCHR-2- C4H3S)2 (R = H, Me): Synthesis, properties and reaction chemistry

Ferrocenyl–triazole complexes and their use in heavy metal cation sensing

“…This included exploring the significance of H⋯N, H⋯O, and π⋯π stacking interactions in establishing the configuration of the extended structure. 95–100 Fig. 4 shows the Hirshfeld surfaces mapped over the d norm of 3 , 7 , and 9 .…”

“…This included exploring the signicance of H/N, H/O, and p/p stacking interactions in establishing the conguration of the extended structure. [95][96][97][98][99][100] For each compound, in the crystal packing the bright and deep-red spot in the Hirshfeld surface indicates the closest distance between the atoms at the exterior (d e ) and interior (d i ) of the compound. Fingerprint plots (Fig.…”

Structural Chemistry of Titanium (IV) Oxo Clusters, Part 2: Clusters without Carboxylate or Phosphonate Ligands

“…A representative example is Ti 6 O 9 L 6 [L=2‐(benzoxazol‐2‐yl)‐4,6‐bis ( t‐ butyl) phenolate] [85] . Each Ti atom is coordinated to a chelating ligand L. A few clusters in which both Ti 3 O 3 subunits are capped by POM “ligands” [86] as well as the cyclopentadienyl derivative Ti 6 O 9 (C 5 H 4 SiMe 3 ) 6 [87] have the same core structure. Note the difference to the aforementioned Ti 6 O 5 clusters, where the six Ti atoms also form a trigonal prism.…”