In this paper we introduce and study so-called k * -metrizable spaces forming a new class of generalized metric spaces, and display various applications of such spaces in topological algebra, functional analysis, and measure theory.By definition, a Hausdorff topological space X is k * -metrizable if X is the image of a metrizable space M under a continuous map f : M → X having a section s : X → M that preserves precompact sets in the sense that the image s(K) of any compact set K ⊂ X has compact closure in X.Contents 42 13. The structure of sequential k * -metrizable groups 47 References 49 1 Proposition 1.3. Let X, Y be topological spaces such that X is µ-complete and each compact subset of Y is sequentially compact. A function s : Y → X is precompact-preserving if and only if s is cs * -continuous.Proof. The "only if" part is trivial and holds without any assumptions on X and Y . To prove the "if" part, assume that s : Y → X is a cs * -continuous function from a space Y whose all compact subsets are sequentially compact into a µ-complete space X. To show that s is precompact-preserving, take any compact subset K ⊂ Y . We claim that the image s(K) is precompact. Assuming that it is not so, we get that s(K) is not bounded by the µ-completeness of X. Consequently there is an infinite locally finite family U = {U n : n ∈ ω}