Total Syntheses of (^|^minus;)-Actumine

Furuta, Miyu

doi:10.5059/yukigoseikyokaishi.72.72

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2016

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“…[2] In the realm of synthetic organic chemistry, they are routinely employed for a variety of acid‐catalyzed reactions due to their solubility in water, alcohols, ionic liquids, etc. The notable acid‐catalyzed general reactions include esterification of acids and peptides, [4, 5] dehydration of alcohols, protection of carbonyl compounds as acetals/ketals, etc. In recent times, they are also being explored for synthesis of metal‐organic frameworks (MOFs) in view of their wide ranging chemical and physical properties.…”

Section: Introductionmentioning

confidence: 99%

Oxidation of thiols to sulphonic acids with Oxone^®/NaHCO₃ and KBrO₃

2016

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The reagent system Oxone /NaHCO 3 is shown to be very convenient for direct conversion of thiols to sulfonic acids. The simple procedure that involves stirring of thiol, Oxone /NaHCO 3 in CH 3 CN-H 2 O (3:2, v/v) mixture at 20 AE 5 8C allows access to a variety of aliphatic as well as electron rich and deficient ar-omatic sulfonic acids. The oxidation is also shown to occur with KBrO 3 , albeit over longer durations. The mechanism of thiol-tosulfonic acid oxidation with Oxone is proposed to proceed via electron transfer steps, which is supported by the formation of disufide at low conversions.

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Section: Introductionmentioning

confidence: 99%