2019
DOI: 10.1002/ange.201900454
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Total Synthesis of Carthamin, a Traditional Natural Red Pigment

Abstract: The first total synthesis of carthamin (3), a historic natural red pigment, has been achieved. The molecular structure was efficiently constructed by assembling two equivalents of the in situ generated lithiated monomers and triisopropyl orthoformate. This synthesis confirms the structure proposed in 1996.

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Cited by 1 publication
(2 citation statements)
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“…Twelve chemical components were initially identified. Among them, carthamin has a characteristic absorption wavelength at 520 nm [11]. According to the value of VIP, HSYA, carthamin, kaempferol‐3‐ O ‐β‐D‐rutinoside, 6‐hydroxykaempferol‐3,6‐di‐ O ‐β‐D‐glucoside, and AHSYB had significant changes.…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…Twelve chemical components were initially identified. Among them, carthamin has a characteristic absorption wavelength at 520 nm [11]. According to the value of VIP, HSYA, carthamin, kaempferol‐3‐ O ‐β‐D‐rutinoside, 6‐hydroxykaempferol‐3,6‐di‐ O ‐β‐D‐glucoside, and AHSYB had significant changes.…”
Section: Resultsmentioning
confidence: 99%
“…Safflower contains both red and yellow pigments, and the pigments extracted from the safflower have an ancient history. Carthamin, the main component of red pigment [11], was mainly used in cosmetics and clothes before aniline appeared. Nowadays, red pigment is widely used in color chocolate because of its low solubility in water.…”
Section: Introductionmentioning
confidence: 99%