We have documented more than 200 relative values of gold and silver across almost 3000 years (2500 bce–400 ce) to establish value benchmarks for essentially pure metal. Our aim is to improve understanding of ancient economies by enabling regional and temporal comparisons of these relative values. First, we establish silver as an early, reliable benchmark for valuing gold of varying purity before implementation of parting. Whilst purity accounted for two to threefold variation in the value of gold, we conclude that availability was more influential. Access to Nubian gold until about 1100 bce seems an important influence on gold-silver value ratios in Egypt and the Near East, which increased significantly following loss of this source. This investigation yields a suite of relative values for essentially pure gold and silver, subdivided by regions and intervals from 2500 bce–400 ce. These will enable future comparisons of precious metal-denominated costs of labour and commodities, including with today.