Electroluminescent devices (ELDs) were fabricated using GaNO crystallites. The GaNO crystallites were obtained by the oxidation of GaN crystallites before their annealing in vacuum. Although the cathodoluminescence spectra of GaNO crystallites were broad compared with those of GaN crystallites, the spectral intensities of GaNO crystallites are higher than those of GaN crystallites. In the fabrication of lightemission layers in the ELDs, sedimentation with the selection of GaNO crystallite size was performed. The size selection of GaNO crystallites is effective for the realization of thin and uniform emission layers. It leads to the reduction of operating voltage.