1992
DOI: 10.1080/00304949209355895
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TRANSFORMATION OF CARBOXYLIC ESTERS TO ALDEHYDES WITH LITHIUMtris(DIETHYLAMINO)ALUMINUM HYDRIDE

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Cited by 8 publications
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“…During recent decades, the development of catalytic processes in organic synthesis has become a research area of great importance. While the metal-catalyzed hydrogenation , and hydrosilylation of ketones are well-established processes, in the related reduction of lactones to the corresponding lactols (eq 1) the use of a stoichiometric amount of a metal hydride has remained mandatory. Several modified aluminum hydrides have been reported to accomplish the partial reduction of lactones and esters, and diisobutylaluminum hydride (DIBAL-H) is currently the reagent of choice . However, a disadvantage with the standard reaction conditions is the low temperature required, usually −78 °C (eq 1).…”
Section: Introductionmentioning
confidence: 99%
“…During recent decades, the development of catalytic processes in organic synthesis has become a research area of great importance. While the metal-catalyzed hydrogenation , and hydrosilylation of ketones are well-established processes, in the related reduction of lactones to the corresponding lactols (eq 1) the use of a stoichiometric amount of a metal hydride has remained mandatory. Several modified aluminum hydrides have been reported to accomplish the partial reduction of lactones and esters, and diisobutylaluminum hydride (DIBAL-H) is currently the reagent of choice . However, a disadvantage with the standard reaction conditions is the low temperature required, usually −78 °C (eq 1).…”
Section: Introductionmentioning
confidence: 99%