“…In a situation where the temperature of the cold wall stays below the freezing point, the thickness of the frozen layer increases with time. 83,84 In latent heat thermal energy storage (LHTES) systems using PCMs, the heat flux through the material typically reduces when the solidification process starts because convective heat transfer is suppressed. The reduction in heat transfer rate during solidification can increase the duration of energy storage and, thus, reduce the system's efficiency.…”