A method is explained through which a pointwise accurate approximation to the pion's valencequark distribution amplitude (PDA) may be obtained from a limited number of moments. In connection with the single nontrivial moment accessible in contemporary simulations of latticeregularised quantum chromodynamics (QCD), the method yields a PDA that is a broad concave function whose pointwise form agrees with that predicted by Dyson-Schwinger equation analyses of the pion. Under leading-order evolution, the PDA remains broad to energy scales in excess of 100 GeV, a feature which signals persistence of the influence of dynamical chiral symmetry breaking. Consequently, the asymptotic distribution, ϕ asy π (x), is a poor approximation to the pion's PDA at all such scales that are either currently accessible or foreseeable in experiments on pion elastic and transition form factors. Thus, related expectations based on ϕ asy π (x) should be revised.PACS numbers: 14.40. Be, 12.38.Aw, 12.38.Gc, 12.38.Lg The light-front wave-function of an interacting quantum system, ϕ(x), provides a connection between dynamical properties of the underlying relativistic quantum field theory and notions familiar from nonrelativistic quantum mechanics. In particular, although particle number conservation is generally lost in relativistic quantum field theory, ϕ(x) has a probability interpretation. It can therefore translate features that arise purely through the infinitely-many-body nature of relativistic quantum field theory into images whose interpretation seems more straightforward [1][2][3].With ϕ(x) in hand, the impact of phenomena that are essentially quantum field theoretical in origin may be expressed via wave-function overlaps. Such overlaps are familiar in all disciplines and associated with a longestablished interpretation. For example, the (leadingtwist) wave-function of a meson is an amplitude that describes the momentum distribution of a quark and antiquark in the bound-state's simplest (valence) Fock state. The amplitude, ϕ(x), is a process-independent expression of intrinsic properties of the composite system. Seemingly, the simplest composite systems in nuclear and particle physics are the pions. This isospin triplet of (unusually) low-mass states are constructed from valence u-and d-quarks. As a process-independent expression of pion properties, ϕ π (x) is a crucial element in computing the leading-twist and leading-order in α-strong results for pion elastic and transition form factors [4][5][6]. For many years, predictions obtained with such formulae have served as motivation for crucial experiments designed to test QCD; e.g., Refs. [7][8][9][10][11][12][13].Regarding the pion, however, appearances have long been deceiving. The unusually low mass of these states signals the intimate connection between dynamical chiral symmetry breaking (DCSB) and the existence and properties of pions. This connection is fascinating because DCSB is a striking emergent feature of QCD, which plays a critical role in forming the bulk of the visi...