1985
DOI: 10.1016/0010-8545(85)80022-9
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Transition metal complexes of semicarbazones and thiosemicarbazones

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Cited by 771 publications
(279 citation statements)
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“…The calculated values of the ligand field parameters lie in the range reported for an octahedral structure [35,36]. Also, the values of the magnetic moment (3.2-3.7 B.M.)…”
Section: Resultssupporting
confidence: 58%
See 1 more Smart Citation
“…The calculated values of the ligand field parameters lie in the range reported for an octahedral structure [35,36]. Also, the values of the magnetic moment (3.2-3.7 B.M.)…”
Section: Resultssupporting
confidence: 58%
“…This frequency was shifted to the lower frequency in the spectra of the complexes which was indicated the coordination of the carbonyl oxygen atom to the central metal ions. This is further confirmed by the appearance of the new band at 515-525 and 425-430 cm −1 due to the ν(M-N) and ν(M-O) [35,36]. The NMR spectrum of the ligand was done in DMSO-d 6 .…”
Section: Resultsmentioning
confidence: 72%
“…A number of authors [19][20][21][22][23] were interested to investigate the biological and medicinal properties of transition metal complexes of thiosemicarbazones. Thomas and Parmeswaran [20] studied the antitumour activities of Mn 2+ , Co 2+ , Ni 2+ , and Cu 2+ chelates of anthracene-9-carboxaldehyde thiosemicarbazone.…”
Section: Biological Propertiesmentioning
confidence: 99%
“…Thiosemicarbazones are now well established as an important class of sulfur donor ligands particularly for transition metal ions [1][2][3]. This is due to remarkable biological activities observed for these compounds, which has since been shown to be related to their metal complexing ability.…”
Section: Introductionmentioning
confidence: 99%
“…Heterocyclic thiosemicarbazones capable of tridentate coordination have been studied extensively, [1][2][3][4][5] and in recent years many reports involve crystal structures of these thiosemicarbazones and/or their metal complexes. 6 Also, the structures of bis(thiosemicarbazones) capable of tetradentate coordination and their complexes have been the subject of numerous recent reports.…”
Section: Introductionmentioning
confidence: 99%