Transition-Metal Complexes with Nano-Sized Phosphine and Pyridine Ligands-Catalysis, Fluxional Behavior and Molecular Recognition

Obora, Yasushi; Tokunaga, Makoto; Tsuji, Yasushi

doi:10.1007/s10563-005-9160-5

Cited by 3 publications

(2 citation statements)

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“…A nanodevice is containing several different segments which are connected together with a precise in atomic or molecular level 42–44. Multifunctional macromolecules are able to deliver several segments in the same time and are good candidates to construct the nanodevices.…”

Section: Introductionmentioning

confidence: 99%

“…19,[38][39][40][41] A nanodevice is containing several different segments which are connected together with a precise in atomic or molecular level. [42][43][44] Multifunctional macromolecules are able to deliver several segments in the same time and are good candidates to construct the nanodevices. However due to their synthesis routes, perfect dendrimers are containing only one or two types of functional groups on their surfaces 19,[38][39][40][41] which have the same reactivity and selec-tive reactions for constructing nanodevices is difficult.…”

Section: Introductionmentioning

confidence: 99%

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Dendritic macromolecules containing several types of functional groups

Adeli

Zarnegar

Kabiri

2009

J of Applied Polymer Sci

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Dendritic macromolecules containing several types of functional groups were successfully synthesized through divergent method. Poly(ethylene glycol) was functionalized using cyanuric chloride and it was reacted with p‐toluidine at room temperature and a macromolecule containing chloride and methyl functional groups (PEG‐Cl2‐Me2) was obtained. Substitution of chloride functional groups of PEG‐Cl2‐Me2 by hydroxyl functional groups led to a macromolecule containing methyl and hydroxyl functional groups (PEG‐Me2‐OH4). Hydroxyl functional groups of PEG‐Me2‐OH4 were reacted with cyanuric chloride and PEG‐Me2‐Cl8 was obtained. Finally, PEG‐Me2‐Cl8 was reacted with p‐aminophenol at room temperature and a macromolecule containing methyl, hydroxyl, and chloride functional groups (PEG‐Me2‐(PhOH)4‐Cl4) was obtained. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010

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Section: Introductionmentioning

confidence: 99%