Transition metal derivatives of 1,10-phenanthroline-5,6-dione: Controlled growth of coordination polynuclear derivatives

Calucci, Lucia; Pampaloni, Guido; Pinzino, Calogero; Prescimone, Alessandro

doi:10.1016/j.ica.2006.04.040

Cited by 30 publications

(33 citation statements)

References 77 publications

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“…The strong absorption band centered at 487 nm (a) is assigned to n π* of the C=O group of phendione ligand. The three bands centered at 253, 293 and 314 nm (b) are assigned to ligand centered (π π*) transitions [6,[20][21][22]. The solvent dependency of n π* energy on the solvent polarity, a well known phenomenon, is the reason behind such an assignment [17,22].…”

Section: A Subhan Et Al J Sci Res 7(3) 113-128 (2015) 117mentioning

confidence: 99%

“…The metal complexes with the ligand containing heterocyclic ring systems are very promising candidates for such applications [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15][16][17]. The ongoing interests in the pharmacological field for the development of better therapeutic agents which can bind and damage DNA is rationalized by the fact that many diseases, including cancer occur because of aberrant gene expression.…”

Section: Introductionmentioning

confidence: 99%

“…Our recent study is concerning phendione ligands, which is originated from phenanthroline [2,3]. Phendione based metal complex chemistry has been growing rapidly due to promising electrical, optical and biological applications [4][5][6][7][8][9][10][11][12][13][14][15][16][17][18][19][20][21][22][23]. In our present study we reported the synthesis of several metal complexes containing phendione ligand with their characterization, optical as well as biological properties.…”

Section: Introductionmentioning

confidence: 99%

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Spectroscopic Investigations, Anti-bacterial Activities and DNA-interactions of Metal Complexes (Cr(III), Zn(II), Ni(II)) Containing Phendione Ligand

Subhan

Ahmed²,

Rahaman³

et al. 2015

J. Sci. Res.

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The transition metal complexes [Cr(acac) 2 were synthesized from 1, 10-phenanthroline-5, 6-dione (phendione). The phendione ligands and its metal complexes were characterized by FTIR, UV-Visible spectroscopy, PL study and in some cases by GC-MS. The red emission band of complex [Zn(acac) 2 (phendione)] was observed by excitation at 250 nm. DNA binding activities of the complexes were studied by DNA Gel Electrophoresis. DNA binding studies of the synthesized compounds showed that the metal complexes are strong DNA binding and cleaving agents. The [Ni(phendione) 2 ] (ClO 4 ) 2 complex was the most effective DNA binding and cleaving agent and [Cr(acac) 2 (phendione)]Cl complex shows relatively lower affinity to the DNA. The metal complexes easily cause DNA degradation or cleavage (after 2.5 h) with genomic DNA rather than plasmid DNA. Antimicrobial activity studies revealed that all metal complexes of phendione showed efficient resistance to bacteria. The [Cr(acac) 2 (phendione)]Cl complex showed most potential antimicrobial activities against the bacteria Escherichia coli with an annular radius of the inhibitory zone, 4.33.

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Section: A Subhan Et Al J Sci Res 7(3) 113-128 (2015) 117mentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Spectroscopic Investigations, Anti-bacterial Activities and DNA-interactions of Metal Complexes (Cr(III), Zn(II), Ni(II)) Containing Phendione Ligand

Subhan

Ahmed²,

Rahaman³

et al. 2015

J. Sci. Res.

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“…The obtained yellow suspension was cooled to rt, gradually poured into 1 kg ice, and pH of the mixture was raised up to 6 by adding 30% NaOH. The final yellow mixture was extracted with dichloromethane, dried on anhydrous Na 2 SO 4 , recrystallized from hot methanol, and dried in air [41]. Yield: 7.15 g (68%), mp 257 °C.…”

Section: Synthesis Of 110-phenanthroline-56-dione (Step 1)mentioning

confidence: 99%

A rational synthesis of a novel imidazo[4,5-f][1,10]phenanthroline templated Schiff base: Characterization, photoluminescence and DFT/TD-DFT study

Karslıoğlu¹,

Demir²,

Yilmaz³

et al. 2017

Bull. Chem. Soc. Eth.

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H-NMR, IR, elemental analysis and electrospray ionization mass spectroscopy (ESI-MS) techniques. Solid state emission spectrum of impap showed two distinct strong emission maxima with large Stokes shifts. The ground state gas phase geometry of impap was predicted by DFT calculations. Excited state properties of the molecule were examined through TD-DFT calculations conducted at the optimized geometry. Responsible transitions for the strong fluorescence of impap were assigned to single component charge transfer transitions with large oscillator strengths based on the ground state calculated molecular orbital contributions.

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“…The presence of two electronegative * heteroatoms creates not only the basic properties in the Lewis sense but also, because of the resonance conjugation, makes it possible to alter the electron density in different parts of the molecule, especially by interaction of an external electrophile with unshared pairs of electrons of the heteroatom [4]. Therefore, pdon is a building block in binuclear or multinuclear complexes through reaction via a diiminic binding site and through an o-quinoid group [5].…”

Section: Introductionmentioning

confidence: 99%

Preparation and separation of mixed-ligand Fe(II) complexes containing 1,10-phenanthroline-5,6-dione as ligand

Kobetić

Denžić

Zimmermann

et al. 2012

Journal of Coordination Chemistry

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The synthesis, separation, and characterization of mixed-ligand iron(II) complexes containing 1,10-phenanthroline (phen), 1,10-phenanthroline-5,6-dione (pdon), and NCS À are reported. The mixed-ligand complexes [Fe(phen)(pdon) 2 ] 2þ and [Fe(phen) 2 (pdon)] 2þ were prepared from iron(II) sulfate hepta hydrate and both ligands. The mixture of both complexes formed regardless the ratio of the ligands or the reaction time; therefore, the complexes were separated successfully on the reversed phase (RP) Develosil RP-Aqueous [C30] 5 mm, 150 Â 4.6 mm column by two different methods. The first method was the ion paired RP chromatography performed under gradient elution with acetonitrile-water containing 0.001 mol L À1 KPF 6 aqueous as mobile phases. The second method was the RP chromatography performed under gradient elution with methanol and water as mobile phases. The gradient elution with watermethanol as eluents was preferred for the semi preparative separations allowing one to use the complexes without further purification upon separation, different than the first method and its variations so far. Three complexes (5, 6, and 7) were characterized by electrospray ionization mass spectrometry, NMR, UV-Vis, and IR.

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Transition metal derivatives of 1,10-phenanthroline-5,6-dione: Controlled growth of coordination polynuclear derivatives

Cited by 30 publications

References 77 publications

Spectroscopic Investigations, Anti-bacterial Activities and DNA-interactions of Metal Complexes (Cr(III), Zn(II), Ni(II)) Containing Phendione Ligand

Spectroscopic Investigations, Anti-bacterial Activities and DNA-interactions of Metal Complexes (Cr(III), Zn(II), Ni(II)) Containing Phendione Ligand

A rational synthesis of a novel imidazo[4,5-f][1,10]phenanthroline templated Schiff base: Characterization, photoluminescence and DFT/TD-DFT study

Preparation and separation of mixed-ligand Fe(II) complexes containing 1,10-phenanthroline-5,6-dione as ligand

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