Transition metal iodates. I. Preparation and characterization of the 3d iodates

Study of XRD, FT-IR and Nonlinear Optical Properties of Doped and Undoped Barium Iodate Crystals Grown in Silica Gel

“…Fundamental frequencies of the pyramidal iodate ions as have been reported earlier by Nassau et al [14], Dasent and Waddington [15], Balicheva and Petrova [16], Sanyal and Nag [17], and Nyquist and Kagal [18] are in good agreement with the observed values. Table 2 represents the vibrational frequencies for the undoped and doped barium iodate crystals.…”

Square‐Planar Noble Metal Iodate [M(IO3)4]n– (M = PdII, AuIII; n = 2, 1) Anions and Their Ability to Form Polar and Centrosymmetric Architectures

“…Iodate compounds have been the subject of intense interest because of their propensity for adopting noncentrosymmetric structures that are often polar, [1][2][3][4][5][6][7][8] a feature that is aptly illustrated by A[MoO 3 (IO 3 )] (A = Rb, Cs), [9] A[(VO) 2 -(IO 3 ) 3 O 2 ] (A = NH 4 , Rb, Cs), [10] and NaYI 4 O 12 . [11] This structural attribute can be exploited in the development of new nonlinear optical, pyroelectric, piezoelectric, and ferroelectric materials, with the first property being the most heavily investigated.…”

Promising Material for Infrared Nonlinear Optics: NaI3O8 Salt Containing an Octaoxotriiodate(V) Anion Formed from Condensation of [IO3]− Ions

“…[1][2][3][4][5][6][7][8] In the 1970s, metal iodates had been extensively studied at Bell Laboratories for their NLO properties but also for their ferroelectric, piezoelectric, and pyroelectric properties. [9][10][11][12][13][14] Interest for iodate compounds resumed in the beginning of the 2000s. The work of Albrecht-Schmitt and co-workers was mainly devoted to actinide iodates regarding their radiation stability.…”