Therefore, it has been widely used in the manufacturing of transistors, [4][5][6] micro/nano sensors, [7,8] flexible electronics, [9][10][11][12][13] and biomaterials, [14][15][16][17][18] etc. The E-Jet printing is a "pull" processing that uses an extra electric field to significantly improve resolution. When an appropriate electrical potential is applied to the extraction electrode at the outlet of a nozzle, a jet with a stable shape (Taylor cone) will be formed as a result of the balance of the electric field force, surface tension force, and gravity force. Different E-Jet printing modes (e.g., dropon-demand E-Jet, direct-writing E-Jet, and electrospray) can be realized by carefully adjusting the ink flux, the standoff height (nozzle-to-substrate distance), and the applied voltage, relying on a stable electrostatic field between the nozzle and the substrate. However, the E-Jet printing is hard to be applied in curved substrates due to the unstable electric field distribution caused by the variation of standoff height. Some scholars were concerned about this issue. Seong and his colleagues built the experimental setup to maintain a uniform electric field strength by implementing 3D movements of the nozzle to keep a constant standoff height during the printing. [19] Nevertheless, it is still difficult to control the jet with precision and consistency because the direction of the electric field varies with the relative position of the nozzle-substrate.In addition to curved substrates, the conductivity of the substrate is also an important factor affecting the E-Jet printing. Substrates with good electrical conductivity are often chosen because they can quickly direct residual charges away from the deposited droplets, thus improving the accuracy of the printed structures. In comparison, insulating substrates can severely degrade printing accuracy and resolution, and even interrupt the follow-on printing behavior. [20][21][22][23][24] That is because the polarization of the substrate under a strong electric field and the charge accumulation of the deposited droplets can change the electric field distribution between the substrate and the nozzle. Researchers have proposed ways to improve printing accuracy on insulating substrates. Dong and his coworkers presented an AC-pulse modulated E-Jet printing technology that can alternate the charge polarity of the consequent droplets to neutralize the residue charge on the substrate, which enables high-resolution printing of continuous patterns. [25] Wang et al. improved Electrohydrodynamic jet (E-Jet) printing is one of the most effective methods for fabricating micro/nanostructures due to its high-resolution, broad material adaptability, and simple process. However, printing high-resolution patterns on curved or insulated substrates still is of a great challenge because it is quite difficult to keep the electric field distribution stable between the nozzle and the substrate during the printing process. To address these issues, a dual-ring electrostatic focused electrohydro...