“…The usually reported κ values are just within 0.1–0.6 W m –1 K –1 for non-conducting polymer thin films. − Even though much higher κ values are possible to achieve at the nanoscale, they are observed only for single-polymer chains, i.e., for polymers in the form of nanotubes or nanowires. − For the 3D structures, especially for branched polymers, which are our azo polymer samples, κ values are usually below 1 W m –1 K –1 . − This can be explained as follows. The heat transport in the non-conducting materials can be described in terms of phonons created by lattice vibrations that propagate through them. , It is known that polymers are not crystalline structure materials and do not have a long-range order. However, if there is at least a short-range order, the description of the heat transport via the phonons is still valid. , The phonon mean free path ( L ) is significantly reduced in polymers compared to pure crystalline materials, , but still (in some single-polymer chains), an efficient path for phonon transport with weak scattering can be achieved .…”