“…In recent years, more and more coal energy industries in China have been developing advanced coal chemical technologies to cope with the increased demand for energy . Coal gasification was expected to become the promising technology for clean fuel such as methanol, alcohol and gas, however, the coal gasification wastewater (CGW) generated in the gas washing, condensing and purifying processes contains high concentrations of ammonia, cyanide, thiocyanate, phenolic compounds, polycyclic aromatic hydrocarbons, heterocyclic compounds and long‐chain hydrocarbons, which cause serious deterioration of the environment without adequate treatment. For CGW treatment, anaerobic hybrid aerobic processes have been applied, however, the secondary effluent is unable to satisfy reuse standards (main parameters COD < 60 mg L −1 and NH 4 + ‐N < 15 mg L −1 ), due to the high concentration of COD, total phenols (TPh, the main portion of COD) and NH 4 + ‐N.…”