Investigations include alloying the PMHSS6-5-3 steel surface layer with carbide and ceramic powders WC, VC, TiC, SiC, Si3N4 and Al2O3, using the high power diode laser (HPDL). Laser treatment is especially promising for solving contemporary surface engineering problems making it possible to focus precisely the delivered energy in the form of heat in the surface layer. The structural mechanism was determined of surface layers development, effect was studied of alloying parameters, method on structure refinement and influence of these factors on the mechanical properties of surface layer, and especially on its abrasive wear resistance. The fine grained martensite structure is responsible for hardness increase of the alloyed layer. The tribological wear relationships were determined for laser treated surface layers, determining friction coefficient, and wear trace shape developed due to the abrasive wear of the investigated surfaces. Comparison of the laser treatment parameters and tribological properties of surface layer after remelting and alloying with hard particles of the PMHSS6-5-3 steel using the high power diode laser to obtain the optimum service properties is the outcome of the investigations carried out.