The well-known alumina ceramics have extensive structural application due to its outstanding physico-mechanical properties like hardness, wear resistance, good thermal conductivity, and thermal and chemical stability even at high temperature. 1 Its typical application includes in various engineering fields such as laser tubes, cutting tools, wear pads, high temperature electrical insulators, electronic substrates, automobiles, especially in unlubricated engines, aerospace, and even in biomaterials. 2-7 However, the fracture toughness of alumina ceramics is low, as a result, the material becomes brittle and thus its application reduces. Numerous research has been carried out to improve tribological behavior in conformal contact by incorporation of oxides like CuO, Y 2 O 3, ZrO 2, MgO, TiO 2 , Nb 2 O 3 8-12 and nonoxides like SiC, TiN, TiB 2 ,CNT 13 etc as a secondary phase in alumina matrix. Valefi et al 14 investigated the effect of CuO addition into yttria stabilized tetragonal zirconia polycrystalline (Y-TZP) ceramics sliding against alumina ball in conformal contact. They reported that the coefficient of friction (COF) reduces to 0.35 with a low wear rate (<10 −6 m 3 /N m) due to accumulation of soft copper oxide layer which causes shifting of the wear mechanism from brittle to ductile and increases wear resistance. The effect of different lubricating additives like TiC, CNT, CaF 2 etc to improve tribological attributes of alumina and alumina-zirconia composite up to a certain level of addition and range of temperature by reinforcement in the matrix was also reported by several researchers. 15-18 Countersurface plays an essential role on COF Kerkwijk et al 10 have reported that COF changes from 0.65 to 0.43 when Al 2 O 3 ball is replaced by Y-TZP ball as a counter surface on 5 wt.% CuO added alumina sintered. The tribo-mechanical properties of CuO/3Y-TZP composite system sliding upon Al 2 O 3