Tricarbonyl‐(1‐phenylborinato)manganese

Herberich, Gerhard E.; Becker, Hans Jürgen

doi:10.1002/anie.197307641

Cited by 31 publications

(5 citation statements)

References 7 publications

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“…Similarly, the observation that the CO stretching frequencies in 1-phenylborabenzene manganese tricarbonyl (XII) are 19 cm-1 higher than those for CflHsMn(CO)3 also supports this model (17).…”

Section: Mn(co>3 (Xii)mentioning

confidence: 53%

Borabenzene anion and its transition metal complexes

Allen¹,

Palmer²

1978

J. Chem. Educ.

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Section: Mn(co>3 (Xii)mentioning

confidence: 53%

Borabenzene anion and its transition metal complexes

Allen¹,

Palmer²

1978

J. Chem. Educ.

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“…The CO stretching frequencies in the IR spectrum of 43c in hexane are 2039, 1966, and 1948 cm −1 , which are virtually identical with those of (1-phenylboratabenzene)Mn(CO) 3 . In contrast, the CO stretching frequencies of CpMn(CO) 3 are 2028 and 1944 cm −1 . These data suggest that boratabenzene and 1,2-oxaborolyl are weaker donors but better acceptors than Cp.…”

Section: 2-oxaborolylmentioning

confidence: 72%

“…In contrast, 42c is a robust crystalline compound which is stable in most common solvents at room temperature. The CO stretching frequencies in the IR spectrum of 43c in hexane are 2039, 1966, and 1948 cm −1 , which are virtually identical with those of (1-phenylboratabenzene)Mn(CO) 3 . In contrast, the CO stretching frequencies of CpMn(CO) 3 are 2028 and 1944 cm −1 .…”

Section: 2-oxaborolylmentioning

confidence: 77%

Aromatic Borataheterocycles: Surrogates for Cyclopentadienyl in Transition-Metal Complexes

Ashe

2009

Organometallics

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This review describes the syntheses and coordination chemistry of selected unsaturated borataheterocycles. These compounds are formally derived from common heteroaromatic rings by the isoelectronic substitution of an anionic BHgroup for a neutral CH group. Specifically included are the five-membered rings 1,2-and 1,3-thiaborolyls, derived from thiophene, 1,2-oxaborolyl, derived from furan, and 1,2-azaborolyl, derived from pyrrole. Also included is the six-membered ring 1,2-azaboratabenzene, derived from pyridine. These anionic rings can serve as surrogates for cyclopentadienyl in organometallic compounds.

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“…Finally we note that the CO stretching frequencies in the IR spectrum of 12b in hexane are 2039, 1966, and 1948 cm -1 , which are virtually identical to those of 13 (2039, 1974, 1960 cm -1 ), but are slightly shifted from those of CpMn(CO) 3 (2028, 1944 cm -1 ). This suggests that the boron heterocycles are weaker donors but better acceptors than Cp 8b…”

mentioning

confidence: 61%