Trigonostemon species in south China: Insights on its chemical constituents towards pharmacological applications

Song, Kainan; Li, Meichen; Yang, Yin; Zhang, Zhe; Zhang, Jun; Zhu, Qing; Liu, Jianyu; Wang, Andong

doi:10.1016/j.jep.2021.114504

Journal of Ethnopharmacology

2021

DOI: 10.1016/j.jep.2021.114504

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Trigonostemon species in south China: Insights on its chemical constituents towards pharmacological applications

Kainan Song

Meichen Li

Yin Yang

et al.

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Cited by 4 publications

(1 citation statement)

References 68 publications

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“…Given that some DDOs contained a trans -diol moiety, we attempted to convert 30 into a useful trans -diol compound. Exposure of 30 to TBAF unmasked the TES group to afford 31 , which was subsequently converted into the corresponding benzoate 32 .…”

mentioning

confidence: 99%

Asymmetric Construction of the Core of C₆, C₇-Epoxy Daphnane Diterpenoid Orthoesters

Sun,

Feng,

Qin

et al. 2023

Org. Lett.

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Asymmetric construction of the core of C6, C7-epoxy daphnane diterpenoid orthoesters is developed through a convergent synthetic strategy. The salient features include a diastereoselective nucleophilic assembly of two bulky cyclic fragments, an oxidative cleavage/transesterification/aldol cascade to fashion the seven-membered ring, and a base-mediated transesterification/retro-aldol/aldol/epoxidation cascade to install the epoxy moiety with proper stereochemistry.

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mentioning

confidence: 99%

Asymmetric Construction of the Core of C₆, C₇-Epoxy Daphnane Diterpenoid Orthoesters

Sun,

Feng,

Qin

et al. 2023

Org. Lett.

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Chemical constituents from the stems of Ostodes paniculata Bl. (Euphorbiaceae)

Yang,

Mao,

et al. 2024

Biochemical Systematics and Ecology

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Highly Aromatic Norditerpenoid Heterodimers and Monomers from Trigonostemon fragilis

Zhou,

Cheng,

Gao

et al. 2024

Engineering

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Trigonostemon species in south China: Insights on its chemical constituents towards pharmacological applications

Cited by 4 publications

References 68 publications

Asymmetric Construction of the Core of C₆, C₇-Epoxy Daphnane Diterpenoid Orthoesters

Asymmetric Construction of the Core of C₆, C₇-Epoxy Daphnane Diterpenoid Orthoesters

Chemical constituents from the stems of Ostodes paniculata Bl. (Euphorbiaceae)

Highly Aromatic Norditerpenoid Heterodimers and Monomers from Trigonostemon fragilis

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Trigonostemon species in south China: Insights on its chemical constituents towards pharmacological applications

Cited by 4 publications

References 68 publications

Asymmetric Construction of the Core of C6, C7-Epoxy Daphnane Diterpenoid Orthoesters

Asymmetric Construction of the Core of C6, C7-Epoxy Daphnane Diterpenoid Orthoesters

Chemical constituents from the stems of Ostodes paniculata Bl. (Euphorbiaceae)

Highly Aromatic Norditerpenoid Heterodimers and Monomers from Trigonostemon fragilis

Contact Info

Product

Resources

About

Asymmetric Construction of the Core of C₆, C₇-Epoxy Daphnane Diterpenoid Orthoesters

Asymmetric Construction of the Core of C₆, C₇-Epoxy Daphnane Diterpenoid Orthoesters