This chapter furnishes the plasmonic properties of metal nanostructure and its application to thin-film solar cell. Plasmonics is an emerging branch of nanooptics where light metal interaction in subwavelength domain is studied. Metal supports surface plasmon resonance that has tunable signature, which depends on the morphology as well as surrounding media. These plasmonic resonances can be tuned in a broader range of solar spectra by changing several parameters such as size, shape and medium. Moreover, metals show scattering properties that could be utilized to enhance optical path length of photon inside the thin film of solar device. The chapter mainly focusses on the study of plasmonic resonance of smaller-and larger-sized metal nanoparticle using semi-analytical as well as numerical approach. For the estimation of optical properties like extinction spectrum and field profile of larger-sized nanoparticle, finite-difference time-domain (FDTD) method is used. The field distribution in both silver and gold nanoparticle cases has been plotted in 'on' resonance condition, which has a broader range of applications.