Tuning the stereoelectronic factors of iron(ii)-2-aminophenolate complexes for the reaction with dioxygen: oxygenolytic C–C bond cleavage vs. oxidation of complex

Abstract

Modular tuning of stereoelectronic factors of Iron(ii)-2-aminophenolate complexes during the reaction with dioxygen enables to control oxygenolytic C–C bond cleavage vs. metal and/or ligand based oxidation.

Synthesis and characterization of a uranyl(vi) complex with 2,6-pyridine-bis(methylaminophenolato) and its ligand-centred aerobic oxidation mechanism to a diimino derivative

“…The aerobic oxidations of coordinating ligands are also known for various transition metal complexes, where a direct interaction between O 2 and a metal centre is always found. 2–6,36,38,37 c ,39 In contrast, the aerobic oxidation of 1 (Fig. 8) is initiated by the interaction between O 2 and the N–H bond of the pdaop 2− ligand, and proceeds only in the ligand side.…”

Biological activity of non-radical vs. stable radical of a pyridazine-sulfonamide aminophenol-type compound

“…It can undergo oxidation to o-iminosemiquinonate and o-iminoquinone, followed by polymerisation to form conducting polymers 5 (Scheme 1). 2-Aminophenolato-appended organic compounds can act as useful redox materials for enzymatic functions (e.g., non-heme extradiol dioxygenases), [5][6][7][8] reactive oxygen species (ROS) scavenging, 9 charge conductance, 10 and sensing studies. 11 Sulfonamides are used widely against microbial infections and have potential activity as anticancer agents, [12][13][14][15] antiglaucoma agents, 16 inhibitors of gamma-secretase, 17 cyclooxgenase-2 and lipoxygenase, anti-convulsant agents, and hypoglycemic agents.…”