We demonstrate a capability for exploring the behavior of hydrogen at a Pd/GaAs (n-type) Schottky interface containing a native oxide. By applying a large forward current to such a hydrogenated interface, a remarkable reduction of the hydrogenation effect was observed. Formation of hydrogen-related electron traps near the interface could be responsible for this reduction of hydrogenation effect. Moreover, evidence was observed for the decomposition of those electron traps when hydrogen was forced to diffuse out from such interfaces.