Gas-phase
low volatility organic compounds (LVOC), produced from
oxidation of isoprene 4-hydroxy-3-hydroperoxide (4,3-ISOPOOH) under
low-NO conditions, were observed during the FIXCIT chamber study.
Decreases in LVOC directly correspond to appearance and growth in
secondary organic aerosol (SOA) of consistent elemental composition,
indicating that LVOC condense (at OA below 1 μg m–3). This represents the first simultaneous measurement of condensing
low volatility species from isoprene oxidation in both the gas and
particle phases. The SOA formation in this study is separate from
previously described isoprene epoxydiol (IEPOX) uptake. Assigning
all condensing LVOC signals to 4,3-ISOPOOH oxidation in the chamber
study implies a wall-loss corrected non-IEPOX SOA mass yield of ∼4%.
By contrast to monoterpene oxidation, in which extremely low volatility
VOC (ELVOC) constitute the organic aerosol, in the isoprene system
LVOC with saturation concentrations from 10–2 to
10 μg m–3 are the main constituents. These
LVOC may be important for the growth of nanoparticles in environments
with low OA concentrations. LVOC observed in the chamber were also
observed in the atmosphere during SOAS-2013 in the Southeastern United
States, with the expected diurnal cycle. This previously uncharacterized
aerosol formation pathway could account for ∼5.0 Tg yr–1 of SOA production, or 3.3% of global SOA.