Courant 1996
DOI: 10.1007/978-0-387-21626-3_22
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Cited by 5 publications
(10 citation statements)
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“…The calculated value of T e (38,581 cm 21 ) for the a 3 P state with the active space of (8,8) is also in good agreement with the experimental value, 16 37,908 6 1613 cm…”
Section: Resultssupporting
confidence: 84%
See 1 more Smart Citation
“…The calculated value of T e (38,581 cm 21 ) for the a 3 P state with the active space of (8,8) is also in good agreement with the experimental value, 16 37,908 6 1613 cm…”
Section: Resultssupporting
confidence: 84%
“…Fisher et al 15 obtained 0 K bond dissociation energies of SiF þ 1-4 and adiabatic ionization energies for the SiF 1-4 species using the guided ion beam mass spectrometry. In 1996, Reid 16 obtained the a 3 P cationic state energies and adiabatic electron affinities of SiF by translationalenergy spectroscopy. More recently, Bredohl et al 17 observed three bands with the ionization potentials of 7.31 6 0.02, 15.12 6 0.12, and 17.27 6 0.13 eV, respectively in their study of the vacuum ultraviolet absorption spectra of SiF, which were assigned to three electronic states of SiF þ .…”
Section: Introductionmentioning
confidence: 99%
“…Statistical activated complex theories, namely, the quasiequilibrium theory of mass spectra of Rosenstock et al [9] can, in general, account reasonably well for PICSs in hydrocarbons [10,11], although performs poorly for highly fluorinated or PFC species. The poor performance for PFCs is due to a breakdown of the statistical approximation: Impulsive dissociation may occur directly from some excited states, and hence, fragment ions can exhibit high kinetic-energy release (KER) [12][13][14][15][16][17][18][19][20][21][22][23][24][25]. The inadequacy of statistical models for the PFCs means that accurate experimental characterization of PICSs for such species, in particular, for groups of related structures, is important both for gaining further insight into the fundamental dynamics of ionization and for aiding interpretation of mass spectra in analytical applications.…”
Section: Introductionmentioning
confidence: 99%
“…Configuration interaction calculations have been reported by Robbe (6) Many papers on the ionization of SiF and other diatomic halides of the same group are found in the literature. Reid (11) gives a summary of the results, including his own, for cationic and anionic states of CF, CCl, SiF, and SiCl.…”
Section: Introductionmentioning
confidence: 99%