Most of the existing studies focus on the analysis of college student users of blogs, virtual communities, and other online application platforms, while the research on the motivation of micro-blogging college student users focuses on the research of usage motivation. In this paper, we established a multilevel psychological early warning model based on personality, mood, and emotion space and mapped personality, mood, and emotion to accurately simulate the law of human emotion change for the relevance of micro-blog sentiment analysis to college students' growth development and management. The experiment shows that the method effectively realizes the analysis and description of micro-blog emotion; finally, the designed micro-blog emotion early warning system realizes the visual analysis and timely warning of the psychological condition of the observed subjects, which verifies the effectiveness of the research method.