Two 1D Ladderlike Heterometallic Zinc(II) Coordination Polymers: Syntheses, Crystal Structures, and Fluorescence Properties

Abstract

Abstract. Two coordination polymers [Zn -5,6,14,15-dibenzo-1,4,8,12-tetraazacyclo-pentadeca-7,13-dien; H 2 ipt = isophthalic acid) were synthesized by solvothermal methods and characterized by single-crystal X-ray diffraction. Complexes 1 and 2 exhibit ladderlike

Two 3d-4f Heterometallic Coordination Polymers of Macrocyclic Oxamide with Benzotriazole-5-carboxylate Co-ligand: Syntheses, Crystal Structures and Magnetic Properties

“…Especially, benzotriazole‐5‐carboxylate has five coordination atoms and different bonding modes, which makes it easy to design and construct extended frameworks . In our previous work, although some 3d‐3d′ heterometallic coordination polymers based on macrocyclic oxamide and aromatic multicarboxylate have been obtained, those containing 3d‐4f have been prepared rarely.…”