2019
DOI: 10.1021/acs.nanolett.9b02719
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Two-Dimensional Quadrupole Topological Insulator in γ-Graphyne

Abstract: Two-dimensional quadrupole topological insulator (2D QTI), as a new class of second-order topological phases, has been experimentally confirmed in various artificial systems recently. However, its realization in electronic materials has seldom been reported. In this work, we predict that the experimentally synthesized γ-graphyne is a large-gap (∼0.2 eV) 2D QTI. Three characterized features for 2D QTI are simultaneously observed in γ-graphyne: quantized finite bulk quadrupole moment, gapped topological edge sta… Show more

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Cited by 109 publications
(72 citation statements)
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“…The existence of one-dimensional hinge states has been experimentally confirmed in bismuth [60] and multi-layer WTe 2 [61]. In 2D higher-order TIs, one-dimensional edges are insulating whereas the cor-ners between different edges can host zero-dimensional ingap states that are isolated from both edge and bulk bands by an energy gap [53][54][55][62][63][64][65]. In contrast to the gapless edge states in conventional topological insulators, higherorder topological corner states are not conducting and behave like localized bound states.…”
Section: Introductionmentioning
confidence: 93%
“…The existence of one-dimensional hinge states has been experimentally confirmed in bismuth [60] and multi-layer WTe 2 [61]. In 2D higher-order TIs, one-dimensional edges are insulating whereas the cor-ners between different edges can host zero-dimensional ingap states that are isolated from both edge and bulk bands by an energy gap [53][54][55][62][63][64][65]. In contrast to the gapless edge states in conventional topological insulators, higherorder topological corner states are not conducting and behave like localized bound states.…”
Section: Introductionmentioning
confidence: 93%
“…Figure 3l depicts the profile of corner states, demonstrating their confinement to the corners of the crystal. Other realizations of higher-order TIs have been reported in [332][333][334][335][336][337][338][339][340][341][342][343][344][345][346].…”
Section: Higher-order Topological Insulatorsmentioning
confidence: 99%
“…However, like most higher-order topological states, a material realization of the state is still missing. Currently, the research on higher-order topology is severely hindered by the lack of realistic material candidates 32,[40][41][42][43][44][45][46][47][48] : the only experimentally verified second-order topological insulator material so far is Bi 32 , and features of combined higher-order and weak topol-ogy were reported in Bi 2 TeI 49 . Thus, it is an outstanding challenge to search for suitable existing materials that realize the second-order nodal-line semimetal state.…”
mentioning
confidence: 99%