Two-Photon Optical Properties of Novel Branched Conjugated Derivatives Carrying Benzophenone Moiety with Various Electron Donor-Acceptor Substituent Groups

Abstract

This paper presents a range of novel new branched conjugated dyes containing benzophenone moiety. As compared with those of 4-(p-benzoyl-styrene)yl-4'-(styrene)yl-triphenylamine (C1) and 4-(p-benzoyl-styrene)yl-4'-3,4,5-trimethoxyl-styrene)yl-triphenylamine (C2), the maximal linear absorption and emission wavelength of 4-(p-benzoyl-styrene)yl-4'-(p'-nitro-styrene)yl-triphenylamine (C3) displays red-shifted remarkably, While the fluorescence quantum yields of C3 are lower than those of C1 and C2 in various solvents. The fluorescence lifetimes of the derivatives were measured, and radiative and non-radiative transition constants of the derivatives were calculated. Two-photon absorption (TPA) optical data of the derivatives were measured by Ti:sapphire femtosecond laser tuning from 720 to 880 nm at intervals of 20 nm. TPA induced fluorescence emission of C3 is red-shifted with respected to that of C1 and C2. TPA cross sections of C3 are larger than those of C1 and C2 in various excited laser frequencies. TPA cross section of C2 and C3 are much larger than those of 3,4,5-(trimethoxylstyrene)yl-triphenylamine (C4) and 4-(p-nitrostyrene)yl-triphenylamine (C5) respectively under various near-IR Ti:sapphire femtosecond laser wavelength. C1 and C2 show similar one- and two- photon optical nature. Geometry optimization with ab initio method confirms that C3 has different electron density distribution, the energy levels in frontier orbitals, the dipole moment changes, the absorption and emission spectroscopy from those of C1 and C2. The cyclic voltammograms of the derivatives were detected in methylene chloride at various scan rates, and the energy of frontier orbials were estimated further from the redox potentials.

Supramolecular Interactions of Terpyridine-Derived Cores of Metallomesogen Precursors

“…Ligand L1 was prepared as described earlier [ 4 ]. [2,2′:6′,2″]terpyridine-4′-ol [ 19 ], 2,6-di(pyridin-2-yl)pyridin-4-yl trifluoromethane-sulfonate [ 20 ], 5-ethynyl-1,2,3-trimethoxybenzene [ 21 ], and 5-(bromomethyl)-1,2,3-trimethoxybenzene [ 22 ] were prepared by literature procedures.…”