Über die Alkaloide von Arundo Donax L.

Orechoff, A.; Norkina, S.

doi:10.1002/cber.19350680312

Cited by 21 publications

(5 citation statements)

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“…This report provides an outline of the distribution of these Trp pathway-derived secondary metabolites in the Poaceae. Hordeum vulgare, 34) Avena sativa, 30) Phalaris arundinacea, 31) and Arundo donax, 32) have been reported to accumulate gramine. The presence of gramine in Hordeum brachyantherum and Hakonechloa macra is a new finding, but this is not surprising because closely related species have been shown to accumulate gramine.…”

Section: Discussionmentioning

confidence: 99%

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Distribution of the tryptophan pathway-derived defensive secondary metabolites gramine and benzoxazinones in Poaceae

Kokubo

Nishizaka

Ube

et al. 2017

Bioscience, Biotechnology, and Biochemistry

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The Poaceae is a large taxonomic group consisting of approximately 12,000 species and is classified into 12 subfamilies. Gramine and benzoxazinones (Bxs), which are biosynthesized from the tryptophan pathway, are well-known defensive secondary metabolites in the Poaceae. We analyzed the presence or absence of garamine and Bxs in 64 species in the Poaceae by LC-MS/MS. We found that Hordeum brachyantherum and Hakonechloa macra accumulated gramine, but the presence of gramine was limited to small groups of species. We also detected Bxs in four species in the Pooideae and six species in the Panicoideae. In particular, four species in the Paniceae tribe in Panicoideae accumulaed Bxs, indicating that this tribe is a center of the Bx distribution. Bxs were absent in the subfamilies other than Pooideae and Panicoideae. These findings provide an overview of biased distribution of gramine and Bxs in Poaceae species.

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Section: Discussionmentioning

confidence: 99%

“…29) Multiple species in the Poaceae accumulate these metabolites. The presence of gramine was reported in Avena sativa, 30) Phalaris arundinacea, 31) and Arundo donax 32,33) as well as Hordeum vulgare. 34) Arundo donax is a species in the Arundinoideae subfamily in the PACMAD clade.…”

mentioning

confidence: 97%

Distribution of the tryptophan pathway-derived defensive secondary metabolites gramine and benzoxazinones in Poaceae

Kokubo

Nishizaka

Ube

et al. 2017

Bioscience, Biotechnology, and Biochemistry

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“…Gramine (1, Fig. 2), extracted from the family plant of the Poaceae, is the simplest example of 3-aminomethylindole discovered in biota [6].…”

Section: Introductionmentioning

confidence: 99%

Design and synthesis of multipotent 3-aminomethylindoles and 7-azaindoles with enhanced protein phosphatase 2A-activating profile and neuroprotection

Lajarín-Cuesta

Arribas

Nanclares

et al. 2018

European Journal of Medicinal Chemistry

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“…Von Euler and Hellstrom (114) in 1932 isolated a base from the germ of Swedish barley which they recognized as an indole derivative from the spectroscopic measurements of Hellstrom (115). Later, in 1935, the substance was named gramine (116); in the same year Orechoff and Norkina (289) reported isolation of a similar substance from the Asiatic reed, Arundo donax L., and named their substance donaxine. Von Euler, Erdtman, and Hellstrom (113) showed the two compounds to be identical.…”

Section: H Gramine {Donaxinementioning

confidence: 99%