Über die Hydrazinate einiger Metallsalze

Franzen, Hartwig; Mayer, Otto

doi:10.1002/zaac.19080600120

Cited by 42 publications

(5 citation statements)

References 2 publications

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“…Long ago, it was already observed, that metal(III) chlorides and hydrazine yield metal(II) complexes , . Reduction of Fe III , Cu II , and Hg II occurs also with pentafluorophenylhydrazine in reactions with FeCl 3 , CuCl 2 , and HgCl 2 in ethanol and the complexes 7 – 9 could be isolated:…”

Section: Resultsmentioning

confidence: 99%

“…[8] In the following we present reactions of pentafluorphenylhydrazine with metal halides and with hexacarbonylchromium(0) [Cr(CO) 6 ]. Shortly after the discovery of hydrazine by Curtius in 1894, the latter [9] and others [10] reported several metal halide complexes with hydrazine and phenylhydrazine of type M(NH 2 NHR) 2 X 2 (R = H, [9][10][11][12][13] Ph, [14,15] ), e.g. also K. A. Hofmann in Munich.…”

Section: Introductionmentioning

confidence: 99%

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Syntheses of Transition Metal Complexes of Pentafluorophenylhydrazine

Rieber

Beck

2018

Zeitschrift anorg allge chemie

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Section: Resultsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Syntheses of Transition Metal Complexes of Pentafluorophenylhydrazine

Rieber

Beck

2018

Zeitschrift anorg allge chemie

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“…Hydrazine N 2 H 4 is another ligand of Ni 2+ , leading to tris(hydrazine)nickel(II) [Ni(N 2 H 4 ) 3 ] 2+ . The first coordination compounds of it were discovered over a century ago: the reports on tris(hydrazine)nickel ( (Curtius & Schrader, 1894;Franzen & von Mayer, 1911). It is interesting to note that the latter coordination compound combines an "oxidizer", NO 3 − , and a "fuel", N 2 H 4 , and this makes it a potential energetic material.…”

Section: Introductionmentioning

confidence: 99%

Inorganic chemistry laboratory experiment on an energetic nickel (II) coordination compound, aimed at third-year undergraduate students

Demirci

Bernaud

2020

Chemistry Teacher International

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This inorganic chemistry laboratory experiment, aimed at third-year undergraduate students, focuses on an energetic coordination compound, tris(hydrazine)nickel(II) nitrate [Ni(N2H4)3][NO3]2. As long as the solid is not subject to mechanical stimuli (impact and friction), it can be safely synthesized and handled. In our laboratory conditions (see supplementary information), the experiment includes synthesis of [Ni(N2H4)3][NO3]2 in two different morphologies, visual inspection of the samples, analysis by IR spectroscopy, checking the crystallinity by powder X-ray diffraction, 3D visualization of the crystal structure by means of a free program, and observation by scanning electron microscopy. In that respect, the experiment, as a whole, introduces students to nickel(II) complexes, coordination compounds, energetic materials, sonochemical and morphology-controlled syntheses, and a 3D visualization program for crystal structures and structural models. This laboratory experiment is also proposed in the form of alternate (light) versions so that it can be adopted in another inorganic chemistry laboratory that may have restrictions in terms of equipment, and in another third-year curriculum.

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“…Some promising materials are the long established complexes formed by metal cations with the nitrogen donor ligand, hydrazine [11]. A whole series of products for this ligand with ions of the first series transition metals with a number of oxidizing anions have been prepared [12].…”

Section: Introductionmentioning

confidence: 99%

Investigation of Preparation, Solubility and Stability Properties of Nickel Hydrazine Nitrate (NiHN)

Cartwright

2018

Propellants Explo Pyrotec

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Following an initial, brief, review of the environmental problems associated with the use of lead based primers, and also some of their potential replacements, this study investigated the preparation of the promising, lead free, energetic material nickel hydrazine nitrate by different methods. All three methods trialed produced the same, analytically indistinguishable, compound but with minor changes in visual appearance. The solution properties governing the precipitation process were investigated in a controlled pH titration experiment. Product solubility in a number of common solvents was investigated. Aqueous ammonia and hydrazine hydrate proved the best "non-destructive solvents" for the solid. UV spectroscopy and con-ductivity of the solutions obtained was used as an indicator of the processes involved in the solubility. Using the critical pH conditions for precipitation from aqueous solutions of hydrazine and nickel nitrate the formation constant for the tris hydrazine complex was determined. Also using the solubility of the tris-hydrazine complex in concentrated hydrazine hydrate an equilibrium constant for the formation of the soluble hexa-hydrazine complex from insoluble tris hydrazine complex was determined. These values were compared with similar values for nickel hydrazine complexes with other anions. The origins of these differences were discussed. Further work on controlling and measuring the particle size of the NiHN produced should be considered.

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Über die Hydrazinate einiger Metallsalze

Cited by 42 publications

References 2 publications

Syntheses of Transition Metal Complexes of Pentafluorophenylhydrazine

Syntheses of Transition Metal Complexes of Pentafluorophenylhydrazine

Inorganic chemistry laboratory experiment on an energetic nickel (II) coordination compound, aimed at third-year undergraduate students

Investigation of Preparation, Solubility and Stability Properties of Nickel Hydrazine Nitrate (NiHN)

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