Ueber Sauerstoffactivirung;

Manchot, W.

doi:10.1002/jlac.19013140117

Cited by 42 publications

(20 citation statements)

References 1 publication

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“…(7) proceeds at about 2:0 V, our proposed system produces hydrogen and hydrogen peroxide at lower electric power input in comparison with the conventional production technique shown in Eqs. (1) and (4). Characteristics of these three production techniques are summarized in Table 3.…”

Section: Simultaneous Production System Of Hydrogen and Hydrogen Peromentioning

confidence: 99%

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Proposal for a new system for simultaneous production of hydrogen and hydrogen peroxide by water electrolysis

Ando

Tanaka²

2004

International Journal of Hydrogen Energy

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Section: Simultaneous Production System Of Hydrogen and Hydrogen Peromentioning

confidence: 99%

“…The auto-oxidation (AO) process discovered by Manchot is the most widely used for the synthesis of hydrogen peroxide [3,4]. This method is suitable for the mass production.…”

Section: Introductionmentioning

confidence: 99%

Proposal for a new system for simultaneous production of hydrogen and hydrogen peroxide by water electrolysis

Ando

Tanaka²

2004

International Journal of Hydrogen Energy

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“…Compounds 2, 16,25,26, 33, 56, and 63 were prepared as described in [6]. Compounds 3 [24], 47 [30],p-ethynylaniline [21], p-ethynylnitrobenzene [25], p-ethynyl-N,N-dimethylaniline [26], p-ethynylanisole [27], and p-iodo-N,Ndimethylaniline [28] were prepared by known methods. Anh.…”

Section: Experimental Partmentioning

confidence: 99%

“…678.3309). 27;18.60;18.65;40.07;85.56;92.32;94.81;101.89;102.13;102.56;104.10;104.20;108.76;111.47;116.42;117.09;123.45;129.67;132.44;133.24;147.19;: 676 (100, M'). Anal.…”

Section: Experimental Partunclassified

Donor/Acceptor‐Substituted Tetraethynylethenes: Systematic Assembly of Molecules for Use as Advanced Materials

Tykwinski¹,

Schreiber²,

Carlón³

et al. 1996

Helvetica Chimica Acta

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A comprehensive series of tetraethynylethenes ( = 3,4-diethynyIhex-3-ene-l,S-diynes, TEEs) bearing electrondonating (p-methoxyphenyl or p-aminophenyl) and/or electron-accepting (p-nitrophenyl) groups was prepared via [I'd]-catalyzed Sonogashira cross-coupling reactions. The electronic and photonic properties of these molecules were investigated with a special emphasis on the effects caused by degree and pattern of donor/acceptor substitution around the central TEE core. This analysis showed that intramolecular donor-acceptor interactions, as evidenced by a long-wavelength charge-transfer band, are considerably more effective in TEES 44 and 46, with trans and cis, linearly-conjugated electronic pathways between donor and acceptor, than in 11, with a geminal, cross-conjugated electronic pathway. UVjVIS Spectroscopy revealed a steady bathochromic shift of the longestwavelength absorption band (Amax) as the number of donor-acceptor conjugation paths increased upon changing from his-arylated (11, 44, and 46) to tetrakis-arylated (14, 31, and 35) TEEs. The position of the longest-wavelength absorption was also found to be strongly dependent on the nature of the N-substituents in the R,NC,H,-donor groups. Electronic emission spectroscopic investigations demonstrated a considerable solvent dependency of the fluorescence of donor-acceptor-substituted TEES such as 11 or 44, in agreement with the presence of highly polarized excited states in these molecules. Correspondingly, fluorescence spectra of TEES bearing only donor or acceptor substituents showed little solvent dependency. The large majority of the donor/acceptor-substituted TEEs are thermally and environmentally stable molecules. They can be stored for months as solids in the air at room temperature, and many decompose only upon heating to temperatures above 200°. X-Ray analysis showed the conjugated C-atom scaffolds of 44, 46, and 67 to be essentially planar, whereas the aryl substituents in 28 and 30 are rotated out of the plane of the TEE core by varying degrees. 1.Introduction. -Conjugated organic molecules and polymers show great promise as components for advanced electronic and photonic applications [ 1-31. For the rational design of tailor-made organic materials with specific function, it is necessary to develop a profound understanding of how and to what degree changes in molecular electronic structure affect physical properties [4].Tetraethynylethene ( = 3,4-diethynylhex-3-ene-l,5-diyne, TEE 1) provides a unique C-atom framework for the incorporation of functional groups into planar, fully conjugated, two-dimensional n -chromophores [5-81. Essentially every desired substitution pattern on the TEE core can be achieved through the proficient use of various (trialkylsily1)alkyne-protecting groups. Together, these molecules make up a 'molecular construction kit' which has been readily elaborated into acyclic [9] and cyclic [lo] acetylenic molecular scaffolding, formation of oligomers [9] and polymers [l 11 with the conjugated poly(triacety1ene) backbone, a...

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“…[15] Die erste Anthrachinon-Pilotanlage produzierte rund 30 Tonnen H 2 O 2 im Monat. [16] Je nach Lösungsmittelsystem und Hydrierkatalysator werden mit dieser Methode H 2 O 2 -Konzentrationen zwischen 0.8 und 35 Gew.-% erhalten.…”

Section: Synthese Von H 2 O 2 Indirekte H 2 O 2 -Synthese Mit Anthracunclassified

Palladium‐ und Gold‐Palladium‐Katalysatoren für die Direktsynthese von Wasserstoffperoxid

Edwards

Hutchings

2008

Angewandte Chemie

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Ueber Sauerstoffactivirung;

Cited by 42 publications

References 1 publication

Proposal for a new system for simultaneous production of hydrogen and hydrogen peroxide by water electrolysis

Proposal for a new system for simultaneous production of hydrogen and hydrogen peroxide by water electrolysis

Donor/Acceptor‐Substituted Tetraethynylethenes: Systematic Assembly of Molecules for Use as Advanced Materials

Palladium‐ und Gold‐Palladium‐Katalysatoren für die Direktsynthese von Wasserstoffperoxid

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