Ultrasound and microwave irradiated sustainable synthesis of 5- and 1-substituted tetrazoles in TAIm[I] ionic liquid

Jasim, Saade Abdalkareem; Tanjung, Faisal Amri; Sharma, Sandhir; Mahmoud, Mustafa Z.; Kadhim, Sally B.; Kazemnejadi, Milad

doi:10.1007/s11164-022-04756-z

Cited by 5 publications

(2 citation statements)

References 49 publications

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“…Kazemnejadi et al synthesized the IL 1,1′,1′′‑(1,3,5‑triazine‑2,4,6‑triyl) tris(3‑methyl‑1 H ‑imidazol‑3‑ium) azide (TA[Im][N 3 ]) from 1,1′,1′′‑(1,3,5‑triazine‑2,4,6‑triyl)tris(3‑methyl‑1 H ‑imidazol‑3‑ium) iodide and sodium azide. 93 Further, they evaluated its use as a solvent for the synthesis of 5-substituted 1 H -tetrazoles 107 from various substituted benzonitriles 105 and benzaldehydes 1 using ultrasound and microwave irradiation (Scheme 33 ). As compared to the conventional synthesis, higher yields were observed in the case of microwave irradiation and ultrasound.…”

Section: Construction Of Heterocycles Catalyzed By Ionic Liquidsmentioning

confidence: 99%

“…azide. 92 Further, they evaluated its use as a solvent for the synthesis of 5-substituted 1Htetrazoles ( 107) from various substituted benzonitriles (105) and benzaldehydes (1) using ultrasound and microwave irradiation (Scheme 33). As compared to the conventional synthesis, the higher yields have been observed in case of microwave irradiation rather than those under ultrasound conditions.…”

Section: Kadam Et Al Synthesized 3-(2-carboxyethyl)-1-methyl-imidazol...mentioning

confidence: 99%

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The Synthesis of Nitrogen- and Oxygen-Containing Heterocyclic Scaffolds Assisted by Ionic Liquids: A 2022 Literature Survey

Dhameliya,

Raghani,

Desai

et al. 2023

Synlett

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Heterocycles have gained recognition as vital components in approved drugs, drawing substantial attention from the scientific community. Ionic liquids (ILs) have been utilized for their transformative role in heterocycle synthesis, showcasing distinctive properties that are pivotal in diverse chemical transformations, while also acting as effective catalysts and offering safer alternatives to volatile organic solvents. This review delves into the synthesis of nitrogen- and oxygen-containing heterocyclic structures, employing various ILs such as ammonium, cholinium, DABCO-based, DBU-based, guanidinium, imidazolium, phosphonium, pyridinium, and miscellaneous. They have proven indispensable in facilitating reactions like Fischer-indole synthesis, Biginelli, Knoevenagel condensations and many more. Notably, the recyclability of ILs serves as a valuable asset, aiding in the completion of intricate synthetic pathways, multicomponent reactions, and one-pot syntheses, ultimately enhancing yields. This review seeks to guide researchers in selecting suitable ILs for specific chemical reactions, enabling the synthesis of aza- and/ or oxa-heterocycles described in 2022. This advancement holds promising prospects for drug development and other applications within the domain of heterocyclic chemistry.

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Section: Construction Of Heterocycles Catalyzed By Ionic Liquidsmentioning

confidence: 99%

Section: Kadam Et Al Synthesized 3-(2-carboxyethyl)-1-methyl-imidazol...mentioning

confidence: 99%

The Synthesis of Nitrogen- and Oxygen-Containing Heterocyclic Scaffolds Assisted by Ionic Liquids: A 2022 Literature Survey

Dhameliya,

Raghani,

Desai

et al. 2023

Synlett

View full text Add to dashboard Cite

show abstract

Synthesis of Highly Porous Mn2O3-Doped Fe3O4 NPs with a Dual Catalytic Function Using Asymmetric Water Soluble Mn-Salen Complex as a Reducing Agent and Template: Catalytic Activity over One-Pot Strecker Synthesis from Alcohols in Recyclable TAIm[CN] Ionic Liquid

et al. 2022

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Ultrasound-promoted metal-free homogenous olefins epoxidation and direct conversion of alkenes to cyclic carbonates using catalytic TAIm[X] (X = WO42-, HSO5-) recyclable ionic liquid under mild conditions

Pallathadka

Mohammed

Mahmoud

et al. 2023

Inorganic Chemistry Communications

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Ultrasound and microwave irradiated sustainable synthesis of 5- and 1-substituted tetrazoles in TAIm[I] ionic liquid

Cited by 5 publications

References 49 publications

The Synthesis of Nitrogen- and Oxygen-Containing Heterocyclic Scaffolds Assisted by Ionic Liquids: A 2022 Literature Survey

The Synthesis of Nitrogen- and Oxygen-Containing Heterocyclic Scaffolds Assisted by Ionic Liquids: A 2022 Literature Survey

Synthesis of Highly Porous Mn2O3-Doped Fe3O4 NPs with a Dual Catalytic Function Using Asymmetric Water Soluble Mn-Salen Complex as a Reducing Agent and Template: Catalytic Activity over One-Pot Strecker Synthesis from Alcohols in Recyclable TAIm[CN] Ionic Liquid

Ultrasound-promoted metal-free homogenous olefins epoxidation and direct conversion of alkenes to cyclic carbonates using catalytic TAIm[X] (X = WO42-, HSO5-) recyclable ionic liquid under mild conditions

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