“…The absorption bands of dental structures (enamel, dentin, and cementum) are in the infrared region due to phosphate, carbonate, and hydroxyl groups in the crystalline structure (Fox et al,1992; Klein et al,2005). These absorption bands in the 9.0‐ to 11.0‐μm region coincide closely to the CO 2 laser irradiation (Moshonov et al,2005; Nomelini et al,2009) and hence, the dental hard tissues can efficiently absorb the irradiation from the CO 2 laser (Kwon et al,2005; Moshonov et al,2005). During irradiation, chemical (Chiang et al,2008; Fox et al,1992; Moshonov et al,2005) and morphological (Chiang et al,2008; McCormack et al,1995; Nomelini et al,2009) changes can be induced in the irradiated dental enamel, thereby changing the susceptibility of its modified mineral content to organic acids in the oral environment (Rodrigues et al,2006; Tepper et al,2004).…”