Ultrathin Y₂O₃:Eu³⁺nanodiscs: spectroscopic investigations and evidence for reduced concentration quenching

Abstract

Here, we report the synthesis and spectral properties of ultrathin nanodiscs (NDs) of YO:Eu. It was found that the NDs of YO:Eu with a thickness of about 1 nm can be fabricated in a reproducible, facile and self-assembling process, which does not depend on the Eu concentration. The thickness and morphology of these NDs were determined with small angle x-ray scattering and transmission electron microscopy. We found that the crystal field in these nanoparticles deviates from both the cubic and monoclinic characteristics, albeit the shape of the D → F (J = 0, 1, 2) transitions shows some similarity with the transitions in the monoclinic material. The Raman spectra of the non-annealed NDs manifest various vibration modes of the oleic acid molecules, which are used to stabilise the NDs. The annealed NDs show two very weak Raman lines, which may be assigned to vibrational modes of YO NDs. The concentration quenching of the Eu luminescence of the NDs before annealing is largely suppressed and might be explained in terms of a reduction of the phonon density of states.

Preparation of Bitter Melon-like Ordered Porous Fluorinated Eu3+–Phenanthroline/ZnO Composite with Yellow Light Emission

“…The energy level structure of Eu 3+ is comparative briefness, and almost no cross-relaxation happened between the energy levels. The characteristic interchange energy transfer (ET) caused the concentration quenching of Eu 3+ . − The 18 EZ-160-5 sample had the strongest luminescence intensity, and the Eu 3+ -doped concentration was determined at 18 wt % in this study.…”