A UV vibrational Raman lidar has been built and used to make quantitative measurements of water vapor and aerosol optical properties over Xi'an, China. Vertical profiles of the water vapor mixing ratio and aerosol extinction coefficient are retrieved. The water vapor mixing ratio is calibrated with radiosonde data. The diurnal variations of the water vapor mixing ratio, aerosol extinction coefficient, and aerosol optical depth are obtained. The results obtained in the form of a time-height indicator (THI) display clearly showed the relationship between water vapor and aerosols, in which the gradual enhancement of water vapor density results in aerosol accumulation in the early morning, in particular in the lower troposphere. The seasonal variations of the water vapor mixing ratio and aerosol optical depth over Xi'an were observed and analyzed using the average monthly distribution obtained by lidar for the first time, which will provide useful scientific data and real-time monitoring methods for studying local climate change. #