Eur. J. Org. Chem.

2002

DOI: 10.1002/1099-0690(200207)2002:13<2109::aid-ejoc2109>3.0.co;2-x

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Unconventional Alkoxylation of Pyrazino[2,3-c][1,2,6]thiadiazine 2,2-Dioxides Mediated by N-Halosuccinimides

Nuria E. Campillo

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Cited by 8 publications

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“…Some evidence indicates that the reaction does not involve the 7-halointermediates and may instead be mediated by free radicals, since it can be catalyzed by typical free-radical initiators such as tert-butylhydroperoxide. 146…”

Section: Scheme 81mentioning

confidence: 99%

Applications of N-Chlorosuccinimide in Organic Synthesis

2007

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N-Chlorosuccinimide (NCS) is a versatile reagent and its significance is not limited to chlorination and oxidation. It mediates or catalyzes many chemical reactions, including halocyclizations, formation of heterocyclic systems, formation of new carbon-carbon bonds, rearrangements, and functional group transformations.

“…Some evidence indicates that the reaction does not involve the 7-halointermediates and may instead be mediated by free radicals, since it can be catalyzed by typical free-radical initiators such as tert-butylhydroperoxide. 146…”

Section: Scheme 81mentioning

confidence: 99%

Applications of N-Chlorosuccinimide in Organic Synthesis

2007

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N-Chlorosuccinimide (NCS) is a versatile reagent and its significance is not limited to chlorination and oxidation. It mediates or catalyzes many chemical reactions, including halocyclizations, formation of heterocyclic systems, formation of new carbon-carbon bonds, rearrangements, and functional group transformations.

Unconventional Alkoxylation of Pyrazino[2,3‐c][1,2,6]thiadiazine 2,2‐Dioxides Mediated by N‐Halosuccinimides.

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2002

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For Abstract see ChemInform Abstract in Full Text.

Cyclopentathiadiazines, Cyclohepta‐ and Cyclopentadithiazoles: New Materials and a Rich Heterocyclic Chemistry of Cyclic Enaminonitriles

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et al. 2005

Eur J Org Chem

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Keywords: Sulfur-nitrogen heterocycles / Materials science / Liquid crystals / Radicals / Fused-ring systems 3-Amino-1H-indene-2-carbonitrile and 2-amino-3H-indene-1-carbonitrile reacted with SCl 2 , iBu 3 N and NCS to give benzocyclopenta[1,2,6]thiadiazines, and whilst 2-aminocyclopent-1-enecarbonitrile gave, under the same conditions, a cyclopenta[1,2,6]thiadiazine, its reaction with mixtures of S 2 Cl 2 , SCl 2 and iBu 3 N under different conditions gave, selectively, an isothiazolo [3,4-d]

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