Understanding mechanism driven regioselectivity in zirconium-catalysed hydroaminoalkylation: homoallylic amines from conjugated dienes

Nuñez Bahena, Erick; Hosseini, Kimia; Curto, Sheila Galván; Schafer, Laurel L.

doi:10.1039/d4sc00636d

Chem. Sci.

2024

DOI: 10.1039/d4sc00636d

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Understanding mechanism driven regioselectivity in zirconium-catalysed hydroaminoalkylation: homoallylic amines from conjugated dienes

Erick Nuñez Bahena,

Kimia Hosseini,

Sheila Galván Curto

et al.

Abstract: A change in regioselectivity for group 4 catalysed hydroaminoalkylation gives linear homoallylic amines from conjugated dienes and amines. Isolated reaction intermediates provide mechanistic insight and evidence for reversible C–C bond formation.

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Understanding mechanism driven regioselectivity in zirconium-catalysed hydroaminoalkylation: homoallylic amines from conjugated dienes

Abstract: A change in regioselectivity for group 4 catalysed hydroaminoalkylation gives linear homoallylic amines from conjugated dienes and amines. Isolated reaction intermediates provide mechanistic insight and evidence for reversible C–C bond formation.

Cited by 2 publications

References 62 publications

Direct C(sp³)–H functionalization with aryl and alkyl radicals as intermolecular hydrogen atom transfer (HAT) agents

Direct C(sp³)–H functionalization with aryl and alkyl radicals as intermolecular hydrogen atom transfer (HAT) agents

Exploiting natural complexity for substrate controlled regioselectivity and stereoselectivity in tantalum catalysed hydroaminoalkylation

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Understanding mechanism driven regioselectivity in zirconium-catalysed hydroaminoalkylation: homoallylic amines from conjugated dienes

Abstract: A change in regioselectivity for group 4 catalysed hydroaminoalkylation gives linear homoallylic amines from conjugated dienes and amines. Isolated reaction intermediates provide mechanistic insight and evidence for reversible C–C bond formation.

Cited by 2 publications

References 62 publications

Direct C(sp3)–H functionalization with aryl and alkyl radicals as intermolecular hydrogen atom transfer (HAT) agents

Direct C(sp3)–H functionalization with aryl and alkyl radicals as intermolecular hydrogen atom transfer (HAT) agents

Exploiting natural complexity for substrate controlled regioselectivity and stereoselectivity in tantalum catalysed hydroaminoalkylation

Contact Info

Product

Resources

About

Direct C(sp³)–H functionalization with aryl and alkyl radicals as intermolecular hydrogen atom transfer (HAT) agents

Direct C(sp³)–H functionalization with aryl and alkyl radicals as intermolecular hydrogen atom transfer (HAT) agents