Abstract:Reactions between the arachno-6,9-C 2 B 8 H 14 (1)d icarbaborane and acyl chlorides,R COCl (2), are subject to stereocontrol that completely changes the nature of the reaction products.W hile most chlorides produce the 8-R-nido-7,8,9-C 3 B 8 H 11 (3)t ricarbollides (by skeletal alkylcarbonation = SAC), bulky RCOCls (2; where R = 1-adamantyl, 2a;1 -mesityl, 2b;9 -anthranyl, 2c;1 -naphthyl, 2d)i n1 ,2-dichloroethane (DCE) in the presence of triethylamine at 40-60 8 8Cg ave as eries of entirely different 1-R-2-… Show more
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