2021
DOI: 10.1039/d1cc05080j
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Unusual design strategy for a stable and soluble high-molecular-weight copper(i) arylacetylide polymer

Abstract: Stable and soluble high-molecular-weight copper(I) arylacetylide polymers were obtained by unusual means. Long enough side chain, electron-withdrawing ester groups and chloroform solvent in polymerization can together relate to the solubility...

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“…[33][34][35] However their high crystallization leads to insolubility in any known solvents, which restricts their further applications. Recently, Bian and coworkers grafted a long alkyl ester chain on the para-position of phenylacetylene to achieve soluble poly(Cu-arylacetylide)s. [36] The long alkyl chain overcomes the close accumulations of the Cu-arylacetylide backbone and thereby enhances the solubility in several solvents. The electron-withdrawing ester groups can stabilize the coordination polymer backbone.…”
Section: Research Articlementioning
confidence: 99%
“…[33][34][35] However their high crystallization leads to insolubility in any known solvents, which restricts their further applications. Recently, Bian and coworkers grafted a long alkyl ester chain on the para-position of phenylacetylene to achieve soluble poly(Cu-arylacetylide)s. [36] The long alkyl chain overcomes the close accumulations of the Cu-arylacetylide backbone and thereby enhances the solubility in several solvents. The electron-withdrawing ester groups can stabilize the coordination polymer backbone.…”
Section: Research Articlementioning
confidence: 99%