Uptake of atenolol, carbamazepine and triclosan by crops irrigated with reclaimed water in a Mediterranean scenario

Beltrán, Eulalia María; Pablos, María Victoria; Torija, Carlos Fernández; Porcel, Miguel Ángel; González-Doncel, Miguel

doi:10.1016/j.ecoenv.2020.110171

Cited by 60 publications

(27 citation statements)

References 52 publications

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“…There are only few previous studies that used QuEChERS for the extraction of CECs in radish tissues ( Table 3 ) [8 , 9 , 26 , 27] . To our knowledge there are no studies using HRMS for a such matrix.…”

Section: Methods Validationmentioning

confidence: 99%

“… N.R. QqQ [27] 1.0 d.w. root 10 mL ACN 4 g MgSO 4 , 1 g NaCl - - 45 39-156 0.01-0.32 0.02-0.96 451-(-83) QToF Present study 1.0 d.w. leaves 10 mL ACN 0,1% FA 4 g MgSO 4 , 1 g NaCl 1 g Nacitrate, 0.5 g disodium citrate sesquihydrate - 45 13-147 0.01-0.29 0.02-0.89 260-(-99) QToF …”

Section: Methods Validationmentioning

confidence: 99%

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One-step extraction and analysis of 45 contaminants of emerging concern using QuEChERS methodology and HR-MS in radish leaves and roots

Labad¹,

Montemurro²,

Berisha

et al. 2021

MethodsX

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The scarcity of freshwater has led to a considerable increase of the reuse of reclaimed wastewater for irrigation of field crops [1 , 2] . This practice potentially exposes agricultural produce to a large variety of xenobiotic compounds including contaminants of emerging concern (CECs) which have been widely recognized to be present in wastewater [3] . Common approaches for the extraction of CECs from crops rely on solid-liquid extraction [4] , assisted solvent extraction [5] , ultra-sound solvent extraction [6] and recently QuEChERS (QUick, Easy, CHeap, Effective, Rugged and Safe) [ [7] , [8] – 9] . Here, eight QuEChERS-based methodologies were compared for their suitability to determine 45 CECs in roots and leaves of soil-grown radish. The key points of the method development were: The development of two single-step analytical methods specific for radish root and leaves, after testing eight different approaches using QuEChERS extraction for the quantitation of 45 CECs. The analytical methodology selected requires minimal time and solvent, making it cost-effective. Methods validation were performed at five concentrations levels (2, 5, 10, 50 and 200 ng g −1 ), with low limits of quantification between 0.01 and 0.32 ng g −1 . The two optimized methodologies may be applied to identify large number of compounds of different families in radish crop. However, validation will be needed to quantify compounds different from the target compounds of this paper.

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Section: Methods Validationmentioning

confidence: 99%

Section: Methods Validationmentioning

confidence: 99%

One-step extraction and analysis of 45 contaminants of emerging concern using QuEChERS methodology and HR-MS in radish leaves and roots

Labad¹,

Montemurro²,

Berisha

et al. 2021

MethodsX

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show abstract

“…For example, 3222 mm 3 /year of RWW has been predicted to be reused by the European Union (EU) by 2025. Among the countries of the EU, Spain is the one with the highest rate of RWW reuse, with more than 1200 mm 3 /year [3]. Approximately 71% of RWW in Spain is used for irrigation of agricultural crops.…”

Section: Introductionmentioning

confidence: 99%

Sulfonamides in Tomato from Commercial Greenhouses Irrigated with Reclaimed Wastewater: Uptake, Translocation and Food Safety

et al. 2021

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The presence of antibiotics in crops is mainly caused by their irrigation with reclaimed wastewater and by the use of organic amendments of animal origin. During this work, the fate of sulfonamide antibiotics in tomato crop has been assessed in two commercial greenhouses located in Almería (Spain) irrigated with reclaimed wastewater. Samplings were made annually for two years. Sulfonamides in several parts of the plant (roots, leaves and fruits) as well as reclaimed wastewater, amendments and soils were analyzed by UHPLC-MS/MS. The results showed that sulfonamides accumulated in soils (sulfamethoxazole between 2 and 14 µg Kg−1; sulfadiazine, sulfathiazole, sulfapyridine, sulfamerazine and sulfadimethoxine in concentrations below 1 µg Kg−1) were in the reclaimed wastewater at concentrations in the ng L−1 range. Their distribution in plants depended on the sulfonamide. The sulfonamides detected in tomato were sulfadiazine, sulfapyridine, sulfamethazole, sulfamethoxazole and sulfadimethoxine. Sulfamethoxazole was the antibiotic with highest concentration in tomato fruit, exceeding 30 µg Kg−1. All sulfonamides were below the Acceptable Daily Intake, however, further studies and legislation are needed to assure food safety.

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“…Studies regarding the uptake of PPCPs by plants in the environmental setting are scarce. The majority of investigations concerned with the capabilities of plants to uptake PPCP compounds are usually conducted using a controlled environment or semi-field conditions [103][104][105]. The highest concentrations of PPCP compounds detected in field plant samples are presented in Figure 9.…”

Section: Plant Uptake and Ppcp Concentrations In Plant Tissuesmentioning

confidence: 99%

Pharmaceutical and Personal Care Products in Different Matrices: Occurrence, Pathways, and Treatment Processes

Reyes

Geronimo

Yano

et al. 2021

Water

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The procedures for analyzing pharmaceuticals and personal care products (PPCPs) are typically tedious and expensive and thus, it is necessary to synthesize all available information from previously conducted research. An extensive collection of PPCP data from the published literature was compiled to determine the occurrence, pathways, and the effectiveness of current treatment technologies for the removal of PPCPs in water and wastewater. Approximately 90% of the compiled published papers originated from Asia, Europe, and the North American regions. The incomplete removal of PPCPs in different water and wastewater treatment processes was widely reported, thus resulting in the occurrence of PPCP compounds in various environmental compartments. Caffeine, carbamazepine, diclofenac, ibuprofen, triclosan, and triclocarban were among the most commonly reported compounds detected in water and solid matrices. Trace concentrations of PPCPs were also detected on plants and animal tissues, indicating the bioaccumulative properties of some PPCP compounds. A significant lack of studies regarding the presence of PPCPs in animal and plant samples was identified in the review. Furthermore, there were still knowledge gaps on the ecotoxicity, sub-lethal effects, and effective treatment processes for PPCPs. The knowledge gaps identified in this study can be used to devise a more effective research paradigm and guidelines for PPCP management.

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Uptake of atenolol, carbamazepine and triclosan by crops irrigated with reclaimed water in a Mediterranean scenario

Cited by 60 publications

References 52 publications

One-step extraction and analysis of 45 contaminants of emerging concern using QuEChERS methodology and HR-MS in radish leaves and roots

One-step extraction and analysis of 45 contaminants of emerging concern using QuEChERS methodology and HR-MS in radish leaves and roots

Sulfonamides in Tomato from Commercial Greenhouses Irrigated with Reclaimed Wastewater: Uptake, Translocation and Food Safety

Pharmaceutical and Personal Care Products in Different Matrices: Occurrence, Pathways, and Treatment Processes

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