2021
DOI: 10.21203/rs.3.rs-296153/v1
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Uranyl-catalyzed C-H Alkynylation and Olefination

Abstract: Uranyl cation (UO22+) has been identified as highly oxidizing agent to abstract hydrogen atoms from C-H bonds for the formation of carbon-centered radicals. This work described a photocatalytic strategy to utilize uranyl peroxo complexes for direct alkynylation and olefination of C(sp3) aliphatics. Crystallographic analysis revealed that the in situ generated uranyl peroxide accelerated the reaction.

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