Air pollution by particulate matter (PM) is recognized as a one of the most important environmental issue. A particular attention is being paid to fine PM fraction (PM2.5, PM1.0) due to its detrimental impact on human health and long-term persistence in the air. Presented work is an in-depth bibliometric study on the concentrations and chemical composition of PM2.5 among 27 rural and 38 urban/urban background stations dispersed across the Europe. Obtained results indicate that the chemical composition of PM2.5, in terms of mass concentrations and percentage contribution of main chemical constituents, is relatively different in various parts of Europe. Urban and urban background stations are typically characterized by higher share of total carbon (TC) in PM2.5, compared to rural background sites, mostly pronounced during the heating periods. The share of the secondary inorganic aerosol (SIA) is typically higher at rural background stations, especially in North-Western Europe. In general, the relative contribution of SIA in PM2.5 mass, both at rural and urban background stations, showed more or less pronounced seasonal variation, opposite to Polish measurement sites. Moreover, Poland stands out from the majority of the European stations by strong dominance of total carbon over secondary inorganic aerosol.