Use of acoustic emission to monitor adipic acid crystallization

Abstract

Crystallization is regarded as an important unit operation for separation and purification. However, it is still difficult to control or to optimize the crystallization process due to the complexity of the coupled phenomena taking place simultaneously in the liquid and solid phases. In order to overcome such drawbacks, different analytical technologies have been implemented in the literature for monitoring the key crystallization parameters. In our work, a multi-probe monitoring system composed of acoustic emission, spectroscopic and imaging probes was applied to the crystallization of a model system (an aqueous solution of adipic acid). The crystallization was carried out under vacuum or atmospheric pressures. The goal was to demonstrate the usefulness of the multi-probe system for monitoring the crystallization process, with special attention to the information given by the acoustic emission, in terms of absolute energy, and the spectroscopic probes. Firstly, the influence of the crystal load on the absolute energy is demonstrated. Then, it is shown how the absolute energy can capture the modifications in the crystallization dynamics due to the different experimental conditions. Such dynamics can also be observed from other acoustic emission descriptors.

Monitoring of industrial crystallization processes through image sequence segmentation and characterization

“…It is part of a global framework with the goal of revolutionizing the operation and maintenance of both batch and continuous industrial crystallizers through digital technology and innovative sensor technologies. The project employs various online sensors, including acoustic emission 1 , 2 and imaging, placed within the reactor to provide real-time quantitative data on crystallization. These data are used for monitoring the characteristics of the crystalline population, including crystallization kinetics, crystal morphology, and quantity 3 , 4 …”